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Merck
모든 사진(4)

주요 문서

221775

Sigma-Aldrich

Copper(II) bromide

99%

동의어(들):

brominating agent, Cupric bromide

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About This Item

Linear Formula:
CuBr2
CAS Number:
Molecular Weight:
223.35
EC Number:
MDL number:
UNSPSC 코드:
12161600
eCl@ss:
38150112
PubChem Substance ID:
NACRES:
NA.22

Quality Level

분석

99%

형태

solid

반응 적합성

core: copper
reagent type: catalyst

mp

498 °C (lit.)

density

4.77 g/mL at 25 °C (lit.)

SMILES string

Br[Cu]Br

InChI

1S/2BrH.Cu/h2*1H;/q;;+2/p-2

InChI key

QTMDXZNDVAMKGV-UHFFFAOYSA-L

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일반 설명

Cuprous bromide may be prepared by the reduction of cupric bromide or CuSO4-NaBr. In the molten state, it is grayish brown /greenish brown in color.

애플리케이션

Some reported applications of copper bromide are:
  • catalyst in cross coupling reactions.
  • co-catalyst in Sonogashira coupling.
  • Lewis acid in enantioselective addition of alkynes.
  • reducing agent, when complexed by three molecules of pyridine initiators for the controlled polymerization of styrene, methyl acrylate and methyl methacrylate.

Reductive homocoupling of α-bromo- α- chlorocarboxylates to dimethyl α, α′ dichlorosuccinate derivatives in presence of CuBr/LiOCH3 in methanol has been reported.

관련 제품

제품 번호
설명
가격

픽토그램

CorrosionExclamation markEnvironment

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

개인 보호 장비

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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프로토콜

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자사의 과학자팀은 생명 과학, 재료 과학, 화학 합성, 크로마토그래피, 분석 및 기타 많은 영역을 포함한 모든 과학 분야에 경험이 있습니다..

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