모든 사진(2)
About This Item
Linear Formula:
NbCl5
CAS Number:
Molecular Weight:
270.17
EC Number:
MDL number:
UNSPSC 코드:
12352302
PubChem Substance ID:
NACRES:
NA.23
분석:
99%
양식:
powder
추천 제품
Quality Level
분석
99%
양식
powder
기술
FTIR: suitable
bp
254 °C (lit.)
mp
204.7 °C (lit.)
density
2.75 g/mL at 25 °C (lit.)
SMILES string
Cl[Nb](Cl)(Cl)(Cl)Cl
InChI
1S/5ClH.Nb/h5*1H;/q;;;;;+5/p-5
InChI key
YHBDIEWMOMLKOO-UHFFFAOYSA-I
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일반 설명
Niobium(V) chloride is a yellow crystalline solid with a high melting point. It is widely used in the field of catalysis, semiconductor devices, and batteries. It is a highly specialized Lewis acid in chemical synthesis, activating alkenes for the carbonyl-ene reaction and the Diels-Alder process.
애플리케이션
Niobium(V) chloride can be used:
- As a precursor to prepare K2NbF7:Mn4+ red phosphors for white light-emitting diode(LED) devices.
- As a Lewis acid to synthesize fluorescein dye derivatives for dye-sensitized solar cells.
- As a dopant to enhance the thermoelectric properties of n-type tin selenide.
- As a precursor to synthesize Nb2O5 microspheres and TiNb2O7 nanoparticles as high-rate capability and long-cycle-life anode materials for lithium-ion batteries .
Used to form mixed chloro-aryloxide compounds, such as [Nb(OC6H3-2,6-i-Pr2)2Cl3]2, which form pyridine or phosphine adducts with a distorted six-coordinate geometry.†
신호어
Danger
유해 및 위험 성명서
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
표적 기관
Respiratory system
보충제 위험성
Storage Class Code
8B - Non-combustible corrosive hazardous materials
WGK
WGK 1
개인 보호 장비
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
이미 열람한 고객
Janet R. Clark et al.
Inorganic chemistry, 36(17), 3623-3631 (1997-08-13)
The mixed chloro-aryloxide compounds [M(OC(6)H(3)Pr(i)(2)-2,6)(2)Cl(3)](2) (M = Nb (1a), Ta (1b); both structurally characterized) and [M(OC(6)H(3)Pr(i)(2)-2,6)(3)Cl(2)] (M = Nb (2a), Ta (2b)) react with pyridine (py) and PMe(2)Ph to produce a series of adducts cis-mer-[MCl(3)(OC(6)H(3)Pr(i)(2)-2,6)(2)(L)] (M, L: Nb, py (3a);
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