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Key Documents

195731

Sigma-Aldrich

Iron(0) pentacarbonyl

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동의어(들):

Iron(0) carbonyl, Pentacarbonyliron(0)

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About This Item

Linear Formula:
Fe(CO)5
CAS Number:
Molecular Weight:
195.90
EC Number:
MDL number:
UNSPSC 코드:
12161600
PubChem Substance ID:
NACRES:
NA.22

vapor density

6.74 (vs air)

Quality Level

vapor pressure

35 mmHg ( 25 °C)
40 mmHg ( 30.3 °C)

autoignition temp.

122 °F

반응 적합성

core: iron
reagent type: catalyst

환경친화적 대안 제품 특성

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

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refractive index

n20/D 1.5196 (lit.)

bp

103 °C (lit.)

mp

−20 °C (lit.)

density

1.49 g/mL at 25 °C (lit.)

환경친화적 대안 카테고리

저장 온도

2-8°C

SMILES string

[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/5CO.Fe/c5*1-2;

InChI key

FYOFOKCECDGJBF-UHFFFAOYSA-N

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애플리케이션

Iron(0) pentacarbonyl can be used:
  • As an iron source to synthesize Fe-doped thin TiO2 films.
  • As a ligand to synthesize complexes of gold(I) and Fe(CO)5, silver and Fe(CO)5.
Reactant for:
  • Addition reactions
  • Decomposition via photolysis
  • Preparation of magnetic Fe onion-like fullerene micrometer-sized particles of narrow size distribution via thermal decomposition
  • Preparation of a heptanuclear iron carbonyl cluster used in catalytic hydrosilane reduction of carboxamides

  • Precursor for preparation of Fe nanoparticles for photocatalytic hydrogen evolution under highly basic conditions

픽토그램

FlameSkull and crossbones

신호어

Danger

유해 및 위험 성명서

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 1

Flash Point (°F)

5.0 °F - closed cup

Flash Point (°C)

-15 °C - closed cup

개인 보호 장비

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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문서 라이브러리에서 최근에 구매한 제품에 대한 문서를 찾아보세요.

문서 라이브러리 방문

Plasma enhanced chemical vapor deposition of iron doped thin dioxide films, their structure and photowetting effect.
Sobczyk-Guzenda A, et al.
Thin Solid Films, 589, 605-612 (2015)
Heterobimetallic Complexes Featuring Fe(CO)5 as a Ligand on Gold.
Wang G, et al.
Chemistry?A European Journal, 23(68), 17222-17226 (2017)
Heterobimetallic Silver-Iron Complexes Involving Fe(CO)5 Ligands
Wang G, et al.
Journal of the American Chemical Society, 139(40), 14292-14301 (2017)
Tetsu Mitsumata et al.
The journal of physical chemistry. B, 116(40), 12341-12348 (2012-09-15)
A new class of magnetoelastic gel that demonstrates drastic and reversible changes in storage modulus without using strong magnetic fields was obtained. The magnetic gel consists of carrageenan and carbonyl iron particles. The magnetic gel with a volume fraction of
H Ohoyama et al.
The journal of physical chemistry. A, 115(40), 10888-10893 (2011-09-13)
The atomic alignment effect has been studied for the dissociative energy transfer reaction of metal carbonyls (Fe(CO)(5), Ni(CO)(4)) with the oriented Ar ((3)P(2), M(J) = 2). The emission intensity from the excited metal products (Fe*, Ni*) has been measured as

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