922560

S-(Trifluoromethyl)thianthrenium triflate

≥95%

• Synonym(s): TT-CF₃⁺ OTf^-
• Empirical Formula (Hill Notation): C₁₄H₈F₆O₃S₃
• Molecular Weight: 434.40
• UNSPSC Code: 12352101
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: ≥95%
• form: powder
• mp: 145-148 °C
• functional group: fluoro; thioether; triflate

Description

Application

S-(Trifluoromethyl)thianthrenium triflate (TT-CF₃⁺ OTf^-) is a trifluoromethylation reagent active for a diverse substrate range. Developed by the Ritter Lab, the enchanced activity is accomplished by participation in either nucleophilic, radical, or electrophilic mechanisms depending on the selected reaction conditions, allowing for the introduction of trifluoromethyl moieties to many substrates with a high functional group tolerance.

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Other Notes

Trifluoromethyl Thianthrenium Triflate: A Readily Available Trifluoromethylating Reagent with Formal CF₃⁺, CF₃^•, and CF₃^- Reactivity.

Legal Information

Patent application: EP21169034.2

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319
• Precautionary Statements: P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable