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  • Enantioselective rhodium-catalyzed addition of arylboronic acids to trifluoromethyl ketones.

Enantioselective rhodium-catalyzed addition of arylboronic acids to trifluoromethyl ketones.

Chemical communications (Cambridge, England) (2006-10-07)
Sébastien L X Martina, Richard B C Jagt, Johannes G de Vries, Ben L Feringa, Adriaan J Minnaard
要旨

The catalytic asymmetric 1,2-addition of a series of arylboronic acids to 2,2,2-trifluoroacetophenones is described with high isolated yields (up to 96%) and good enantioselectivities (up to 83% ee) using a rhodium(I)/phosphoramidite catalyst.

材料
製品番号
ブランド
製品内容

Sigma-Aldrich
2-ナフチルボロン酸, ≥95.0%
カタログ番号
容量
在庫状況
単価
数量