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Functional ruthenium(II)- and iridium(III)-containing polymers for potential electro-optical applications.

Functional ruthenium(II)- and iridium(III)-containing polymers for potential electro-optical applications.

Chemical Society reviews (2007-03-28)

Veronica Marin, Elisabeth Holder, Richard Hoogenboom, Ulrich S Schubert

要旨

The need for novel materials with luminescent properties and advanced processing features requires reliable and reproducible synthetic routes for the design of suitable materials, such as e.g. polypyridyl ruthenium(II) and iridium(III)-containing polymers. The most popular ligand for those purposes is the 4,4'-functionalized bipyridine unit. Therefore, several synthetic strategies for the derivatization of the 4,4'-dimethyl-2,2'-bipyridine are highlighted, and in particular functionalities, which enable further covalent linkage to polymeric structures, are discussed in this critical review. Subsequently, the different synthetic strategies for the preparation of polymeric metal-complexes are described, either starting from small functionalized complexes (later covalently attached to the polymer), or from macroligands (subsequently coordinated to the metal ions). The designed materials reveal good processing properties using spin coating and inkjet printing, as well as beneficial electro-optical properties for potential thin functional film applications, such as light-emitting electrochemical cells.

材料

製品番号

ブランド

製品内容

Sigma-Aldrich

イリジウム, powder, 99.9% trace metals basis

Sigma-Aldrich

イリジウム, foil, thickness 0.25 mm, 99.9% trace metals basis

Sigma-Aldrich

イリジウム, evaporation slug, diam. × L 0.6 cm × 1.2 cm, 99.9% trace metals basis

イリジウム, wire reel, 0.5m, diameter 0.5mm, as drawn, 99.9%

イリジウム, wire reel, 0.5m, diameter 0.38mm, as drawn, 99.9%

イリジウム, rod, 25mm, diameter 3.0mm, as drawn, 99.9%

イリジウム, foil, 25x25mm, thickness 0.125mm, as rolled, 99.9%

イリジウム, rod, 25mm, diameter 2.0mm, as drawn, 99.9%

イリジウム, rod, 50mm, diameter 2.0mm, as drawn, 99.9%

イリジウム, foil, light tested, 25x25mm, thickness 0.025mm, as rolled, 99.9%

イリジウム, rod, 50mm, diameter 3.0mm, as drawn, 99.9%

イリジウム, wire reel, 0.05m, diameter 0.8mm, as drawn, 99.9%

イリジウム, wire, straight, 100mm, diameter 0.5mm, as drawn, 99.9%

イリジウム, foil, 25x25mm, thickness 0.15mm, as rolled, 99.9%

イリジウム, foil, 0.025m coil, thickness 0.05mm, coil width .5mm, as rolled, 99.9%

イリジウム, microfoil, disks, 10mm, thinness 0.1μm, specific density 224μg/cm², permanent mylar 3.5μm support, 99.9%

イリジウム, microfoil, disks, 25mm, thinness 0.1μm, specific density 224μg/cm², permanent mylar 3.5μm support, 99.9%

イリジウム, wire reel, 0.1m, diameter 0.15mm, as drawn, 99.9%

イリジウム, wire reel, 0.05m, diameter 0.1mm, as drawn, 99.9%

イリジウム, wire reel, 1m, diameter 0.125mm, as drawn, 99.9%

イリジウム, foil, 0.1m coil, thickness 0.05mm, coil width .5mm, as rolled, 99.9%

イリジウム, foil, light tested, 25x25mm, thickness 0.05mm, as rolled, 99.9%

イリジウム, wire reel, 0.1m, diameter 0.075mm, as drawn, 99.9%

イリジウム, wire reel, 0.2m, diameter 0.125mm, as drawn, 99.5%

イリジウム, wire reel, 0.2m, diameter 0.125mm, as drawn, 99.9%

イリジウム, wire reel, 0.2m, diameter 0.5mm, as drawn, 99.9%

イリジウム, wire reel, 0.3m, diameter 0.5mm, as drawn, 99.9%

イリジウム, wire reel, 2m, diameter 0.125mm, as drawn, 99.9%

イリジウム, wire, straight, 50mm, diameter 1.0mm, as drawn, 99.9%

イリジウム, foil, 25x25mm, thickness 0.25mm, as rolled, 99.9%