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Organophotoredox-Catalyzed Decarboxylative C(sp3)-O Bond Formation.

Journal of the American Chemical Society (2020-01-04)
Shotaro Shibutani, Taiga Kodo, Mitsutaka Takeda, Kazunori Nagao, Norihito Tokunaga, Yusuke Sasaki, Hirohisa Ohmiya
要旨

This manuscript reports a visible-light-mediated organosulfide catalysis that enables the decarboxylative coupling between simple aliphatic alcohol and tertiary or secondary alkyl carboxylic acid-derived redox active esters to produce a C(sp3)-O-C(sp3) fragment. Results of the coupling using other heteroatom nucleophiles such as water, amides, and thiols are also described.

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Sigma-Aldrich
Phenyl-(benzo)phenothiazine