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S5506

Sigma-Aldrich

Sodium nitrate

ReagentPlus®, ≥99.0%

Synonym(s):

Chile salpeter

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About This Item

Empirical Formula (Hill Notation):
NaNO3
CAS Number:
7631-99-4
Molecular Weight:
84.99
EC Number:
231-554-3
MDL number:
MFCD00011119
UNSPSC Code:
12352300
PubChem Substance ID:
329824455
NACRES:
NA.55

Quality Level

200

product line

ReagentPlus®

Assay

≥99.0%

form

powder or crystals

pH

5.5-8 (20 °C, 50 g/L)

mp

306 °C (dec.) (lit.)

SMILES string

[Na+].[O-][N+]([O-])=O

InChI

1S/NO3.Na/c2-1(3)4;/q-1;+1

InChI key

VWDWKYIASSYTQR-UHFFFAOYSA-N

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General description

Sodium nitrate (chile salpeter) is a hygroscopic compound and soluble in water. It is primarily used as an oxidizing agent in organic synthesis. Additionally, sodium nitrate is used in the manufacture of glass and charcoal briquettes, and the synthesis of potassium compounds.

Application

Sodium nitrate is used:
  • To modify hydroxyapatite to prepare heterogeneous catalyst (sodium nitrate/hydroxyapatite) for Claisen–Schmidt condensation process to synthesis of chalcones.
  • In the direct acetoxylation of arenes under an anhydrous environment of TFA (trifluoroacetic acid), acetic acid, and acetic anhydride.
  • As a redox mediator in the selective oxidation of aromatic alcohols in biphase electrolysis at ambient temperature.

Legal Information

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Flame over circleExclamation mark
GHS03,GHS07

Signal Word

Warning

Hazard Statements

H272 - H319

Hazard Classifications

Eye Irrit. 2 - Ox. Sol. 3

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Oxidizing solids
Nitrates
Hazardous rank I
1st oxidizing solid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Journal of controlled release : official journal of the Controlled Release Society, 131(1), 70-76 (2008-08-12)
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Raúl Bescós et al.
Medicine and science in sports and exercise, 44(12), 2400-2409 (2012-07-20)
Supplementation with inorganic nitrate has been suggested to be an ergogenic aid for athletes as nitric oxide donor. The purpose of this study was to determine whether ingestion of inorganic sodium nitrate benefits well-trained athletes performing a 40-min exercise test
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