33120

N,N-Dimethylformamide

puriss. p.a., ACS reagent, reag. Ph. Eur., ≥99.8% (GC)

• Synonym(s): DMF, NSC 5356
• Linear Formula: HCON(CH₃)₂
• CAS Number: 68-12-2
• Molecular Weight: 73.09
• Beilstein: 605365
• EC Number: 200-679-5
• MDL number: MFCD00003284
• UNSPSC Code: 12352111
• PubChem Substance ID: 329754458
• NACRES: NA.21

Properties

• grade: ACS reagent; puriss. p.a.
• Quality Level: 200
• Agency: reag. Ph. Eur.
• vapor density: 2.5 (vs air)
• vapor pressure: 2.7 mmHg ( 20 °C)
• Assay: ≥99.8% (GC)
• form: liquid
• autoignition temp.: 833 °F
• expl. lim.: 15.2 %
• impurities: ≤0.003% free acid (as CH₃COOH); ≤0.005% free alkali (as NH₃); ≤0.005% non-volatile matter; ≤0.1% water (Karl Fischer)
• color: APHA: ≤15
• refractive index: n20/D 1.4290-1.4310; n20/D 1.430 (lit.)
• pH: 7 (20 °C, 200 g/L)
• bp: 152-154 °C; 153 °C (lit.)
• mp: −61 °C (lit.)
• density: 0.948-0.950 g/mL at 20 °C; 0.944 g/mL (lit.)
• cation traces: Al: ≤0.5 mg/kg; B: ≤0.02 mg/kg; Ba: ≤0.1 mg/kg; Bi: ≤0.1 mg/kg; Ca: ≤0.5 mg/kg; Cd: ≤0.05 mg/kg; Co: ≤0.02 mg/kg; Cr: ≤0.02 mg/kg; Cu: ≤0.02 mg/kg; Fe: ≤0.1 mg/kg; K: ≤0.5 mg/kg; Li: ≥0.1 mg/kg; Mg: ≤0.1 mg/kg; Mn: ≤0.02 mg/kg; Mo: ≤0.1 mg/kg; Na: ≤1 mg/kg; Ni: ≤0.02 mg/kg; Pb: ≤0.1 mg/kg; Sn: ≤0.1 mg/kg; Sr: ≤0.1 mg/kg; Zn: ≤0.1 mg/kg
• SMILES string: [H]C(=O)N(C)C
• InChI: 1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3
• InChI key: ZMXDDKWLCZADIW-UHFFFAOYSA-N

Description

General description

N,N-Dimethylformamide (DMF) is commonly employed as a solvent for various organic reactions. DMF is a useful solvent employed for the isolation of chlorophyll from plant tissues. It is widely employed reagent in organic synthesis. It plays multiple roles in various reactions such as solvent, dehydrating agent, reducing agent as well as catalyst. It is a multipurpose building block for the synthesis of compounds containing O, -CO, -NMe₂, -CONMe₂, -Me, -CHO as functional groups.

Application

N,N-Dimethylformamide (DMF) may be employed as a solvent in the following studies:

• Extraction of chlorophyll containing pigments from the intact tissues of cotyledons of Cucumis sativus.
• Isolation of chlorophyll a from the cell cultures of unicellular marine algae.4
• As reducing agent and solvent for the preparation of Au@Ag core-shell nanocrystals.

Solvent for many hydrophobic organic compounds.

Packaging

2.5 L also available in PE-bottles

Other Notes

The article number 33120-4X2.5L-M will be discontinued. Please order the single bottle 33120-2.5L-M which is physically identical with the same exact specifications.
The article number 33120-4X2.5L-R will be discontinued. Please order the single bottle 33120-2.5L-R which is physically identical with the same exact specifications.
The article number 33120-6X1L-M will be discontinued. Please order the single bottle 33120-1L-M which is physically identical with the same exact specifications.
The article number 33120-6X1L-R will be discontinued. Please order the single bottle 33120-1L-R which is physically identical with the same exact specifications.

Safety Information

• Pictograms: GHS02,GHS08,GHS07
• Signal Word: Danger
• Hazard Statements: H226,H312 + H332,H319,H360D
• Precautionary Statements: P210 - P280 - P303 + P361 + P353 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B
• Storage Class Code: 3 - Flammable liquids
• WGK: WGK 2
• Flash Point(F): 135.5 °F - closed cup
• Flash Point(C): 57.5 °C - closed cup