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Key Documents

Safety Information

94907

Sigma-Aldrich

4-Vinylbenzyl chloride

technical, ≥90% (GC), contains 0.1% total stabilizer

Synonym(s):

4-(Chloromethyl)styrene

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About This Item

Linear Formula:
H2C=CHC6H4CH2Cl
CAS Number:
Molecular Weight:
152.62
Beilstein:
2204384
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

grade

technical

Quality Level

Assay

≥90% (GC)

form

liquid

contains

0.05% 4-tert-butylcatechol as stabilizer
0.05% nitroparaffin as stabilizer
0.1% total stabilizer

refractive index

n20/D 1.572 (lit.)
n20/D 1.572

bp

229 °C (lit.)

density

1.083 g/mL at 20 °C
1.083 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

ClCc1ccc(C=C)cc1

InChI

1S/C9H9Cl/c1-2-8-3-5-9(7-10)6-4-8/h2-6H,1,7H2

InChI key

ZRZHXNCATOYMJH-UHFFFAOYSA-N

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Application

  • Influence of functional group concentration on hypercrosslinking of poly (vinylbenzyl chloride) PolyHIPEs: The research investigates how the concentration of 4-vinylbenzyl chloride affects the hypercrosslinking and properties of PolyHIPEs, enhancing their macroporosity (Koler et al., 2021).
  • Optimization of Synthesis of Poly (vinylbenzyl chloride) by RAFT Polymerisation: This study optimizes the RAFT polymerization conditions for synthesizing poly (vinylbenzyl chloride), analyzing the effect of different isomers in the reaction (Allozy & Abd Karim, 2021).
  • Effect of styrene addition on chemically induced grafting of 4-vinylbenzyl chloride onto low-density polyethylene: This paper explores the effects of styrene addition on the graft polymerization of 4-vinylbenzyl chloride onto polyethylene, aiming to improve the material′s properties for use in anion exchange membranes (Chen et al., 2019).
  • Synthesis and characterization of potentially polymerizable amine-derived ionic liquids bearing 4-vinylbenzyl group: The research focuses on synthesizing new amine-derived ionic liquids with 4-vinylbenzyl groups, evaluating their polymerizability and potential applications in materials science (Zajac et al., 2019).

Pictograms

Skull and crossbonesCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

219.2 °F - closed cup

Flash Point(C)

104 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

94907-VAR:
94907-50ML:
94907-BULK:
94907-250ML:


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Tien D Ho et al.
Analytica chimica acta, 843, 18-26 (2014-08-26)
Super elastic nitinol (NiTi) wires were exploited as highly robust supports for three distinct crosslinked polymeric ionic liquid (PIL)-based coatings in solid-phase microextraction (SPME). The oxidation of NiTi wires in a boiling (30%w/w) H2O2 solution and subsequent derivatization in vinyltrimethoxysilane

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