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Safety Information

779342

Sigma-Aldrich

Glycidyl methacrylate

≥97.0% (GC)

Synonym(s):

GMA, 2,3-Epoxypropyl methacrylate, Methacrylic acid 2,3-epoxypropyl ester

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About This Item

Empirical Formula (Hill Notation):
C7H10O3
CAS Number:
106-91-2
Molecular Weight:
142.15
Beilstein:
2506
EC Number:
203-441-9
MDL number:
MFCD00005137
UNSPSC Code:
12352100
PubChem Substance ID:
329768028
NACRES:
NA.22

Quality Level

200

Assay

≥97.0% (GC)

form

liquid

contains

~0.01% hydrochinone monomethylether as stabilizer

refractive index

n20/D 1.449 (lit.)
n20/D 1.450

bp

189 °C (lit.)

density

1.075 g/mL at 20 °C
1.042 g/mL at 25 °C (lit.)

SMILES string

CC(=C)C(=O)OCC1CO1

InChI

1S/C7H10O3/c1-5(2)7(8)10-4-6-3-9-6/h6H,1,3-4H2,2H3

InChI key

VOZRXNHHFUQHIL-UHFFFAOYSA-N

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Application

Glycidyl methacrylate (GMA) is an epoxy-functional monomer generally used to derivatize polymers. It can also undergo polymerization to form poly (glycidyl methacrylate).

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Repr. 1B - Skin Corr. 1C - Skin Sens. 1 - STOT RE 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

168.8 °F - closed cup

Flash Point(C)

76 °C - closed cup

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PDSCL

Deleterious substance

PRTR

Class II Designated Chemical Substances

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

779342-500ML:4548173361284
779342-BULK:
779342-100ML:4548173361277
779342-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
BCCH1019
BCCF8304
BCCC8906
BCCC1877
BCCB4757

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Biologically active polymers: synthesis and antimicrobial activity of modified glycidyl methacrylate polymers having a quaternary ammonium and phosphonium groups.
Kenawy E-R, et al.
Journal of Controlled Release : Official Journal of the Controlled Release Society, 50(1-2), 145-152 (1998)
Effect of glycidyl methacrylate (GMA) on the thermal, mechanical and morphological property of biodegradable PLA/PBAT blend and its nanocomposites.
Kumar M, et al.
Bioresource Technology, 101(21), 8406-8415 (2010)
Liang Yuan et al.
Biosensors & bioelectronics, 38(1), 79-85 (2012-07-07)
A novel label-free immunosensing strategy for sensitive detection of tumor necrosis factor-alpha antigen (TNF-α) via surface-initiated atom transfer radical polymerization (SI-ATRP) was proposed. In this strategy, the Au electrode was first modified by consecutive SI-ATRP of ferrocenylmethyl methacrylate (FMMA) and
Amir H Milani et al.
Biomacromolecules, 13(9), 2793-2801 (2012-08-11)
The use of injectable pH-responsive doubly cross-linked microgels (DX microgels) to improve the mechanical properties of degenerated intervertebral discs is demonstrated for the first time. The microgel comprised methyl methacrylate (MMA), methacrylic acid (MAA), ethyleneglycol dimethacrylate (EGD) and glycidyl methacrylate
Liang Yuan et al.
Analytical chemistry, 83(17), 6800-6809 (2011-08-03)
A signal amplification strategy for sensitive detection of tumor necrosis factor-alpha (TNF-α) using quantum dots (QDs)-polymer-functionalized silica nanosphere as the label was proposed. In this approach, silica nanospheres with good monodispersity and uniform structure were employed as carriers for surface-initiated
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