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45664

Supelco

Sulfotep

PESTANAL®, analytical standard

Synonym(s):

O,O,O′,O′-Tetraethyl dithiopyrophosphate

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About This Item

Empirical Formula (Hill Notation):
C8H20O5P2S2
CAS Number:
3689-24-5
Molecular Weight:
322.32
Beilstein:
1714019
EC Number:
222-995-2
MDL number:
MFCD00026764
UNSPSC Code:
41116107
PubChem Substance ID:
329756878
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CCOP(=S)(OCC)OP(=S)(OCC)OCC

InChI

1S/C8H20O5P2S2/c1-5-9-14(16,10-6-2)13-15(17,11-7-3)12-8-4/h5-8H2,1-4H3

InChI key

XIUROWKZWPIAIB-UHFFFAOYSA-N

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General description

Sulfotep is a non-systemic, aliphatic organophosphate insecticide, fumigant and acaricide, which may cause unanticipated health and ecological problems. It acts as a cholinesterase inhibitor, and is widely used in controlling aphids, spider mites, thrips and whiteflies on glasshouse crops, mushrooms and ornamentals.

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Sulfotep may be used as a reference standard for the determination of the analyte in liquid pesticide formulations using gas chromatography with flame ionization detection (GC-FID).

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Skull and crossbonesEnvironment
GHS06,GHS09

Signal Word

Danger

Hazard Statements

H300 + H310 + H330,H410

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 1 Inhalation - Acute Tox. 1 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

45664-250MG:
45664-100MG:4548173922676
45664-1EA:
45664-BULK:
45664-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
BCCD1941
BCCC3132
BCCB4839
BCBZ2931
SZBE069XV

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Simultaneous gas chromatographic determination of chlorpyrifos and its impurity sulfotep in liquid pesticide formulations.
Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes, 51(11), 736-741 (2016)
The Pesticide Encyclopedia (2014)
Sulfotepp in diazinon and other organophosphorus pesticides.
R Turle et al.
Bulletin of environmental contamination and toxicology, 38(5), 793-797 (1987-05-01)
J I Cacho et al.
Journal of chromatography. A, 1559, 95-101 (2018-01-02)
Nine organophosphorus pesticides (OPPs) were determined in environmental waters from different origins using in situ ionic liquid dispersive liquid microextraction (IL-DLLME). This preconcentration technique was coupled to gas chromatography-mass spectrometry (GC-MS) using microvial insert thermal desorption, an approach that uses
Lili Pan et al.
Environmental science and pollution research international, 25(1), 4-11 (2016-10-01)
Organophosphorus pesticides (OPPs) are used worldwide and pose great risks to human health. However, information on their presence in agricultural soils at regional scale and the associated risks is limited. In this study, an extensive investigation on agricultural soils was
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