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Safety Information

31726

Supelco

Dimethenamid

PESTANAL®, analytical standard

Synonym(s):

2-Chloro-N-(2,4-dimethyl-3-thienyl)-N-(2-methoxy-1-methylethyl)acetamide

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About This Item

Empirical Formula (Hill Notation):
C12H18ClNO2S
CAS Number:
87674-68-8
Molecular Weight:
275.79
Beilstein:
8143313
MDL number:
MFCD01632376
UNSPSC Code:
41116107
PubChem Substance ID:
329753903
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

SMILES string

COCC(C)N(C(=O)CCl)c1c(C)csc1C

InChI

1S/C12H18ClNO2S/c1-8-7-17-10(3)12(8)14(11(15)5-13)9(2)6-16-4/h7,9H,5-6H2,1-4H3

InChI key

JLYFCTQDENRSOL-UHFFFAOYSA-N

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General description

Dimethenamid is a chloroacetamide herbicide mostly used to control broadleaf weeds and annual grasses in crops.

Application

Dimethenamid may have been used as reference standard for pesticide residue analysis from spinach, soybean and orange using supercritical fluid extraction (SFE) followed by GC-MS.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H302,H411

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2

Storage Class Code

10 - Combustible liquids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

JAN Code

31726-BULK:
31726-VAR:
31726-100MG:

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Certificates of Analysis (COA)

Lot/Batch Number
BCCC8935
BCCC7571
SZBF103XV
SZBB165XV
SZB7201XV

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Pesticide multiresidue analysis of 303 compounds using supercritical fluid extraction.
Ono Y
Analytical Sciences, 22(11), 1473-1476 (2006)
José Antonio Rodríguez-Liébana et al.
Journal of environmental management, 217, 592-599 (2018-04-13)
The use of treated wastewaters (TWW) in agriculture is widening in areas suffering drought, such as southern Europe, to preserve freshwater supply for human consumption. The composition of TWW, especially concerning their organic carbon (OC) content, has been demonstrated to
Gabriela K Suszter et al.
Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes, 52(8), 557-563 (2017-05-11)
Pesticide residues were determined in about 120 soil cores taken randomly from the top 15 cm layer of two sunflower fields about 30 days after preemergence herbicide treatments. Samples were extracted with acetone-ethyl acetate mixture and the residues were determined with GC-TSD.
Analytical method for the determination of metolachlor, acetochlor, alachlor, dimethenamid, and their corresponding ethanesulfonic and oxanillic acid degradates in water using SPE and LC/ESI-MS/MS.
Yokley RA et.al.
Analytical Chemistry, 74(15), 3754-3759 (2002)
Rada D Ðurović-Pejčev et al.
Journal of AOAC International (2018-10-17)
Background: The increased use of pesticides leads to permanent pollution of soil, and there is a need for continuous monitoring of these agrochemicals in soil. Objective: Three methods for the simultaneous determination of 12 pesticides belonging to eight chemical groups
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