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31712

Supelco

Fluazifop-P-butyl

PESTANAL®, analytical standard

Synonym(s):

Butyl (R)-2-[4-(5-trifluoromethyl-2-pyridyloxy)phenoxy]propionate

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About This Item

Empirical Formula (Hill Notation):
C19H20F3NO4
CAS Number:
Molecular Weight:
383.36
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

SMILES string

CCCCOC(=O)[C@@H](C)Oc1ccc(Oc2ccc(cn2)C(F)(F)F)cc1

InChI

1S/C19H20F3NO4/c1-3-4-11-25-18(24)13(2)26-15-6-8-16(9-7-15)27-17-10-5-14(12-23-17)19(20,21)22/h5-10,12-13H,3-4,11H2,1-2H3/t13-/m1/s1

InChI key

VAIZTNZGPYBOGF-CYBMUJFWSA-N

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General description

Fluazifop-P-butyl belongs to the arylophenoxypropionate group of graminicides. It is a post-emergence herbicide that acts by inhibiting acetyl-CoA carboxylase enzyme activity, involved in the catalysis of the formation of malonyl-CoA during metabolism of lipids.

Application

Fluazifop-P-butyl may be used as a reference standard for the determination of the analyte:
  • In different varieties of lettuce (Lactuca sativum) by capillary gas chromatography with nitrogen–phosphorus detection (NPD).
  • In tea samples by modified QuEChERS (quick, easy, cheap, effective, rugged, and safe) sample preparation procedure combined with ultra-performance liquid chromatography-electrospray tandem mass spectrometry (UPLC/MS/MS).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Warning

Hazard Statements

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Flam. Liq. 3 - Repr. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

122.0 °F - closed cup - (External MSDS)

Flash Point(C)

50 °C - closed cup - (External MSDS)

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 2 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

31712-VAR:
31712-BULK:
31712-100MG:


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Simplified multiresidue method for determination of pesticide residues in lettuce by gas chromatography with nitrogen- phosphorus detection.
Fenoll J, et al.
Analytical and Bioanalytical Chemistry, 389(2), 643-651 (2007)
Fluazifop-P-butyl (herbicide) affects richness and structure of soil bacterial communities.
Darine T, et al.
Soil Biology and Biochemistry, 81, 89-97 (2015)
Effect of fluazifop-p-butyl treatment on pigments and polyamines level within tissues of non-target maize plants.
Horbowicz M, et al.
Pesticide Biochemistry and Physiology, 107(1), 78- 85 (2013)
A multi-residue method for fast determination of pesticides in tea by ultra performance liquid chromatography- electrospray tandem mass spectrometry combined with modified QuEChERS sample preparation procedure.
Chen G, et al.
Food Chemistry, 125(4), 1406- 1411 (2011)
Evangelia Chronopoulou et al.
Planta, 235(6), 1253-1269 (2011-12-29)
Plant glutathione transferases (GSTs) comprise a large family of inducible enzymes that play important roles in stress tolerance and herbicide detoxification. Treatment of Phaseolus vulgaris leaves with the aryloxyphenoxypropionic herbicide fluazifop-p-butyl resulted in induction of GST activities. Three inducible GST

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