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M81705

Sigma-Aldrich

Dimethyl sulfone

98%

Synonym(s):

Methyl sulfone

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About This Item

Linear Formula:
(CH3)2SO2
CAS Number:
67-71-0
Molecular Weight:
94.13
Beilstein:
1737717
EC Number:
200-665-9
MDL number:
MFCD00007566
UNSPSC Code:
12352100
PubChem Substance ID:
24897231
NACRES:
NA.22

Quality Level

200

Assay

98%

form

crystals

bp

238 °C (lit.)

mp

107-109 °C (lit.)

SMILES string

CS(C)(=O)=O

InChI

1S/C2H6O2S/c1-5(2,3)4/h1-2H3

InChI key

HHVIBTZHLRERCL-UHFFFAOYSA-N

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Application

Dimethyl sulfone (DMSO2) can undergo:
  • Acylation with N-acylbenzotriazoles to synthesize β-keto sulfones.
  • α-Monoarylation via palladium-catalyzed Negishi coupling reaction to synthesize benzylic sulfones.
  • One-step olefination of alcohols in the presence of ruthenium pincer complex as a catalyst.

DMSO2 can also be used as an electrolyte over a wide range of temperatures (110–150°C) for electrodeposition of aluminum.

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

289.4 °F - closed cup

Flash Point(C)

143.00 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

M81705-1KG:
M81705-5G:
M81705-100G:
M81705-VAR:
M81705-500G:
M81705-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
WXBD4131V
WXBD0753V
WXBC9404V
WXBC7924V
WXBC7740V

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Studies on the AlCl3/dimethylsulfone (DMSO2) electrolytes for the aluminum deposition processes.
Jiang T, et al.
Surface and Coatings Technology, 201(14), 6309-6317 (2007)
Efficient conversion of sulfones intoβ-keto sulfones by N-acylbenzotriazoles.
Katritzky AR, et al.
The Journal of Organic Chemistry, 68(4), 1443-1446 (2003)
Direct catalytic olefination of alcohols with sulfones.
Srimani D, et al.
Angewandte Chemie (International ed. in English), 53(41), 11092-11095 (2014)
A Lin et al.
Toxicology letters, 123(2-3), 169-177 (2001-10-20)
Methylsulfonylmethane (MSM) is a widely available 'alternative' medicine. In vivo magnetic resonance spectroscopy (MRS) was used to detect and quantify MSM in the brains of four patients with memory loss and in three normal volunteers all of who had ingested
Palladium-catalyzed Negishi a-arylation of alkylsulfones.
Zhou G, et al.
Tetrahedron Letters, 51(6), 939-941 (2010)
View All Related Papers

Global Trade Item Number

SKUGTIN
M81705-500G4061834062929
M81705-100G4061834062912
M81705-5G4061834062936

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