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771384

Sigma-Aldrich

[1,3-Bis(diphenylphosphino)propane]palladium(II) triflate

Synonym(s):

Pd(OTf)2(dippp)

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About This Item

Empirical Formula (Hill Notation):
C29H26F6O6P2PdS2
CAS Number:
137846-38-9
Molecular Weight:
817.00
UNSPSC Code:
12161600
PubChem Substance ID:
329767493
NACRES:
NA.22

form

solid

Quality Level

100

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

169-183 °C

SMILES string

[Pd++].[O-]S(=O)(=O)C(F)(F)F.[O-]S(=O)(=O)C(F)(F)F.C(CP(c1ccccc1)c2ccccc2)CP(c3ccccc3)c4ccccc4

InChI

1S/C27H26P2.2CHF3O3S.Pd/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;2*2-1(3,4)8(5,6)7;/h1-12,14-21H,13,22-23H2;2*(H,5,6,7);/q;;;+2/p-2

InChI key

MIGUMLGJSGTNOK-UHFFFAOYSA-L

Related Categories

Application

[1,3-Bis(diphenylphosphino)propane]palladium(II) triflate can be used as a catalyst to synthesize phenanthridines by the reaction between 2-halogeno-N-Ms arylamines and benzyl halides/sulfonates via nucleophilic substitution followed by C-H functionalization and aromatization reaction.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

771384-250MG:
771384-BULK:
771384-1G:
771384-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
SHBC7232

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Recent Trends in the Synthesis and Mechanistic Implications of Phenanthridines
Talukdar V, et al.
advanced synthesis and catalysis (2021)
Recent Trends in the Synthesis and Mechanistic Implications of Phenanthridines
Talukdar V, et al.
Advanced Synthesis & Catalysis (2021)

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