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75992

Sigma-Aldrich

Palladium on activated charcoal

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5% Pd basis

Synonym(s):

Pd/C

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About This Item

Linear Formula:
Pd
MDL number:
MFCD03457879
UNSPSC Code:
12141733
eCl@ss:
38191001
PubChem Substance ID:
57652602
NACRES:
NA.22

Quality Level

100

form

powder

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

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Catalysis
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concentration

5% Pd

greener alternative category

, Aligned

SMILES string

[Pd]

InChI

1S/Pd

InChI key

KDLHZDBZIXYQEI-UHFFFAOYSA-N

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Application

Palladium on activated charcoal (Pd/C) is a catalyst used in hydrogenation of alkenes, alkynes, ketones, nitriles, imines, nitro groups, aromatic and heteroaromatic systems. Pd/C also catalyzes phosphination of aryl bromides and triflates with triphenylphines to yield aryl phosphines.
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Pictograms

Flame
GHS02

Signal Word

Danger

Hazard Statements

H228

Hazard Classifications

Flam. Sol. 1

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK

WGK 3

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 2: Flammable solids
Metal powder
Hazardous rank II
1st combustible solid

JAN Code

75992-1G:
75992-VAR:
75992-10G:
75992-BULK:
75992-50G:

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Certificates of Analysis (COA)

Lot/Batch Number
BCCG8103
BCCF3914
BCCD3508
BCCB5609
BCBF8206V

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Synthesis of aryl phosphines by phosphination with triphenylphosphine catalyzed by palladium on charcoal.
Lai, Chi Wai et al.
Tetrahedron Letters, 42(29), 4883-4885 (2001)
Sonogashira coupling of aryl halides catalyzed by palladium on charcoal.
Novak, Zoltan et al.
The Journal of Organic Chemistry, 68(8), 3327-3329 (2003)
Palladium on Carbon.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Examination of the aromatic amination catalyzed by palladium on charcoal.
Komaromi, Anna and Novak, Zoltan
advanced synthesis and catalysis, 352(9), 1523-1532 (2010)
Examination of the aromatic amination catalyzed by palladium on charcoal.
Komaromi, Anna and Novak, Zoltan
Advanced Synthesis & Catalysis, 352(9), 1523-1532 (2010)
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