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746177

Sigma-Aldrich

MIBA

greener alternative

96%

Synonym(s):

5-Methoxy-2-iodophenylboronic acid

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About This Item

Empirical Formula (Hill Notation):
C7H8BIO3
CAS Number:
89694-50-8
Molecular Weight:
277.85
MDL number:
MFCD26793796
UNSPSC Code:
12352103
PubChem Substance ID:
329765746
NACRES:
NA.06

Quality Level

100

Assay

96%

form

solid

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

202-207 °C

functional group

iodo

greener alternative category

, Aligned

storage temp.

2-8°C

SMILES string

OB(O)C1=C(I)C=CC(OC)=C1

InChI

1S/C7H8BIO3/c1-12-5-2-3-7(9)6(4-5)8(10)11/h2-4,10-11H,1H3

InChI key

XQYAEIDOJUNIGY-UHFFFAOYSA-N

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Find details here.

Application

MIBA can be used to promote direct amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.
Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.
Direct Amidation of Carboxylic Acids Catalyzed by ortho-Iodo Arylboronic Acids: Catalyst Optimization, Scope, and Preliminary Mechanistic Study Supporting a Peculiar Halogen Acceleration Effect

Legal Information

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

related product

Product No.
Description
Pricing

901627

Pym-DATB Catalyst

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

746177-BULK:
746177-250MG:4548174000090
746177-1G:4548174000083
746177-VAR:

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Certificates of Analysis (COA)

Lot/Batch Number
MKBW6286V
MKBV7450V
MKBV0801V
MKBS7361V
MKBS2459V

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