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734586

Sigma-Aldrich

2-(2-Bromoisobutyryloxy)ethyl methacrylate

95%

Synonym(s):

2-Methacryloxyethyl 2′-bromoisobutyrate, 2-Methylacrylic acid 2-(2-bromo-2-methylpropionyloxy) ethyl ester, BIEM

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About This Item

Empirical Formula (Hill Notation):
C10H15BrO4
CAS Number:
213453-08-8
Molecular Weight:
279.13
MDL number:
MFCD18785732
UNSPSC Code:
12162002
PubChem Substance ID:
329764911
NACRES:
NA.23

Assay

95%

form

liquid

refractive index

n20/D 1.471

density

1.303 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CC(=C)C(=O)OCCOC(=O)C(C)(C)Br

InChI

1S/C10H15BrO4/c1-7(2)8(12)14-5-6-15-9(13)10(3,4)11/h1,5-6H2,2-4H3

InChI key

QXDYJUSFCUKOQD-UHFFFAOYSA-N

Application

Atom Transfer Radical Polymerization (ATRP) initiator with a methacrylate functionality for branched polymerization, orthogonal polymerization, or other functionalization.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302

Hazard Classifications

Acute Tox. 4 Oral

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

734586-1G:
734586-5G:
734586-BULK:
734586-VAR:

Certificates of Analysis (COA)

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Timothy A von Werne et al.
Journal of the American Chemical Society, 125(13), 3831-3838 (2003-03-27)
A novel approach is presented for manipulating the size and chemistry of nanoscopic features using a combination of contact molding and living free radical polymerization. In this approach a highly cross-linked photopolymer, based on a methacrylate/acrylate mixture, was patterned into

Articles

Functional Biomaterials Synthesized by Double-Head Polymerization Agents

Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.

Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands

We presents an article about Copper(I)-mediated Living Radical Polymerization in the Presence of Pyridylmethanimine Ligands, and the emergence of living radical polymerization mediated by transition metal catalysts in 1995, which was a seminal piece of work in the field of synthetic polymer chemistry.

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

Applying ARGET ATRP to the Growth of Polymer Brush Thin Films by Surface-initiated Polymerization

Protocols

Typical Procedures for Polymerizing via ATRP

Sigma-Aldrich presents an article about the typical procedures for polymerizing via ATRP, which demonstrates that in the following two procedures describe two ATRP polymerization reactions as performed by Prof. Dave Hadddleton′s research group at the University of Warwick.

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