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Safety Information

680982

Sigma-Aldrich

Cyclopropylzinc bromide solution

0.5 M in THF

Synonym(s):

Bromocyclopropylzinc, Cyclopropane, zinc complex, Cyclopropylzinc(II) bromide

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About This Item

Empirical Formula (Hill Notation):
C3H5BrZn
CAS Number:
126403-68-7
Molecular Weight:
186.37
MDL number:
MFCD08741505
UNSPSC Code:
12352103
PubChem Substance ID:
329760740
NACRES:
NA.22

Quality Level

100

concentration

0.5 M in THF

density

0.969 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

Br[Zn]C1CC1

InChI

1S/C3H5.BrH.Zn/c1-2-3-1;;/h1H,2-3H2;1H;/q;;+1/p-1

InChI key

DUXRKEPSNWXJGV-UHFFFAOYSA-M

Application

Active nucleophile in Pd-catalyzed cross-coupling of heteroaryl halides.

Legal Information

Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.

Signal Word

Danger

Hazard Statements

H225,H302,H314,H335,H351

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Supplementary Hazards

EUH014,EUH018,EUH019

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 3

Flash Point(F)

1.4 °F - closed cup

Flash Point(C)

-17 °C - closed cup

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 4: Flammable liquids
Type 1 petroleums
Hazardous rank II
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

680982-VAR:
680982-BULK:
680982-50ML:4548173272535

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Certificates of Analysis (COA)

Lot/Batch Number
SHBP0987
SHBN4848
SHBM6763
SHBM3460
SHBM0187

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Campbell, J. B. et al.
Synthetic Communications, 19, 2265-2265 (1989)

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