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Safety & Regulatory

674575

MacMillan Imidazolidinone OrganoCatalysts Kit I

Name: MacMillan Imidazolidinone OrganoCatalysts Kit I
Brand: ALDRICH

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About This Item

UNSPSC Code:

12352005

eCl@ss:

32161000

NACRES:

NA.22

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Sigma-Aldrich

663107

(2S,5S)-(−)-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone

Sigma-Aldrich

668540

(2S,5S)-(–)-5-Benzyl-3-methyl-2-(5-methyl-2-furyl)-4-imidazolidinone

Sigma-Aldrich

661902

(S)-(+)-2-(tert-Butyl)-3-methyl-4-imidazolidinone trifluoroacetic acid

Sigma-Aldrich

663085

(5S)-(−)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone dichloroacetic acid

Sigma-Aldrich

663069

(5R)-(+)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride

Sigma-Aldrich

661910

(R)-(−)-2-(tert-Butyl)-3-methyl-4-imidazolidinone trifluoroacetic acid

Sigma-Aldrich

A89804

Anthranilamide

Sigma-Aldrich

677019

(S)-α,α-Bis[3,5-bis(trifluoromethyl)phenyl]-2-pyrrolidinemethanol trimethylsilyl ether

Sigma-Aldrich

90460

Triethylenetetramine

Sigma-Aldrich

633089

trans-N,N′-Dimethylcyclohexane-1,2-diamine

Related Categories

Catalysts

Chiral Catalysts & Ligands

Organocatalysts

General description

MacMillan imidazolidinone organocatalysts are metal-free chiral catalysts widely used in enantioselective organic transformations. These organocatalysts are non-toxic, low cost, and robust in simple reaction conditions because of their insensitivity to air and moisture.

Application

MacMillan Imidazolidinone organocatalysts can be used to catalyze various organocatalytic transformation reactions such as 1,3-dipolar cycloadditions, Diels–Alder reaction, Friedel-Crafts alkylations, α-chlorinations, α-fluorinations, and intramolecular Michael reactions to access a high level of enantioselective products. It can also be used in enantioselective photocatalytic reactions, hydride reduction, and Mukaiyama-Michael reaction.

Legal Information

U.S. Pat. 6,369,243 and related patents apply. For research purposes only.

Kit Components Also Available Separately

Product No.

Description

SDS

569763(5S)-(−)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone monohydrochloride, 97% 500 mgSDS

661902(S)-(+)-2-(tert-Butyl)-3-methyl-4-imidazolidinone trifluoroacetic acid, 96% 500 mgSDS

663085(5S)-(−)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone dichloroacetic acid, 97% 500 mgSDS

663107(2S,5S)-(−)-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone, 97% 500 mgSDS

668540(2S,5S)-(–)-5-Benzyl-3-methyl-2-(5-methyl-2-furyl)-4-imidazolidinone, 95% 250 mgSDS

Pictograms

GHS06,GHS05

Signal Word

Danger

Hazard Statements

H301,H315,H318,H335

Precautionary Statements

P280 - P301 + P310 + P330 - P302 + P352 - P305 + P351 + P338 + P310

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.