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665029

Sigma-Aldrich

1-(1-Adamantyl)-3-(2,4,6-trimethylphenyl)imidazolinium chloride

Synonym(s):

1-(1-Adamantyl)-3-(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride

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About This Item

Empirical Formula (Hill Notation):
C22H31ClN2
CAS Number:
639820-61-4
Molecular Weight:
358.95
MDL number:
MFCD08276859
UNSPSC Code:
12352005
PubChem Substance ID:
24884707
NACRES:
NA.22

form

solid

reaction suitability

reagent type: catalyst
reaction type: Ring-Opening Polymerization

mp

263-280 °C

SMILES string

[Cl-].Cc1cc(C)c(N2CC[N+](=C2)C34CC5CC(CC(C5)C3)C4)c(C)c1

InChI

1S/C22H31N2.ClH/c1-15-6-16(2)21(17(3)7-15)23-4-5-24(14-23)22-11-18-8-19(12-22)10-20(9-18)13-22;/h6-7,14,18-20H,4-5,8-13H2,1-3H3;1H/q+1;/p-1/t18-,19+,20-,22-;

InChI key

MJOMRTQWLPXDJQ-ZFCGJYDVSA-M

Application

Reactant for:
  • Preparation of chelated ruthenium alkoxybenzylidene imidazolidene carbene pivalate catalysts for Z-selective olefin metathesis
  • Use in ring-opening metathesis polymerization and ring-closing metathesis reactions via Grubbs catalyst mediated reactions
  • Preparation of adamantyl-substituted N-heterocyclic carbene ligands in second-generation Grubbs-type iridium metathesis catalysis

Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

665029-VAR:
665029-100MG:
665029-500MG:
665029-BULK:

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Certificates of Analysis (COA)

Lot/Batch Number
MKCM0550
MKBL8979V
15429TD

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Articles

NHC-Based Pd Catalysts and Ligands for C–C Bond Formation

Sigma-Aldrich presents an article concerning NHC-based Pd catalysts and ligands for C–C bond formation at sigma-Aldrich.com.

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