Skip to Content
Merck
All Photos(1)

Key Documents

Safety Information

569437

Sigma-Aldrich

tert-Butylsulfinyl chloride

97%

Synonym(s):

1,1-Dimethylethanesulfinyl chloride, 2-Methyl-2-propanesulfinyl chloride, 2-Methylpropane-2-sulfinic chloride, tert-Butylthionyl chloride

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
(CH3)3CS(O)Cl
CAS Number:
Molecular Weight:
140.63
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

refractive index

n20/D 1.4830 (lit.)

bp

53-54 °C/19 mmHg (lit.)

density

1.135 g/mL at 25 °C (lit.)

SMILES string

CC(C)(C)S(Cl)=O

InChI

1S/C4H9ClOS/c1-4(2,3)7(5)6/h1-3H3

InChI key

ZLJKQOWJEZSNBE-UHFFFAOYSA-N

General description

tert-Butylsulfinyl chloride can be synthesized by using tert-butylmagnesium chloride as the starting material via a multi-step synthesis process.

Application

tert-butylsulfinyl chloride can react with primary and secondary amines to form tert-butylsulfinamides, which on oxidation forms base stable tert-butylsulfonamide. It can also react with 1-thiosugars to form the corresponding carbohydrate thionolactones.

Pictograms

FlameCorrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Flam. Liq. 3 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

125.1 °F - closed cup

Flash Point(C)

51.7 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 2 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

569437-VAR:
569437-BULK:
569437-1G:
569437-5G:


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

"One-pot synthesis of carbohydrate thionolactones from 1-thiosugars"
Wilkinson.LB and Fairbanks.JA
Tetrahedron Letters, 49(33), 4941-4943 (2008)
"Tert-butylsulfonyl (Bus), a new protecting group for amines"
Sun P, et al.
The Journal of Organic Chemistry, 62(24), 8604-8608 (1997)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service