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420697

Sigma-Aldrich

N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine

96%

Synonym(s):

N-(Methoxymethyl)-N-(trimethylsilylmethyl)-N-benzylamine, N-Benzyl-N-(methoxymethyl)trimethylsilylmethylamine, Benzyl(methoxymethyl)[(trimethylsilyl)methyl]amine

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About This Item

Linear Formula:
C6H5CH2N(CH2OCH3)CH2Si(CH3)3
CAS Number:
93102-05-7
Molecular Weight:
237.41
MDL number:
MFCD00674005
UNSPSC Code:
12352116
PubChem Substance ID:
24866346
NACRES:
NA.22

Quality Level

100

Assay

96%

form

liquid

refractive index

n20/D 1.492 (lit.)

bp

76 °C/0.3 mmHg (lit.)

density

0.928 g/mL at 25 °C (lit.)

functional group

amine
ether
phenyl

SMILES string

COCN(Cc1ccccc1)C[Si](C)(C)C

InChI

1S/C13H23NOSi/c1-15-11-14(12-16(2,3)4)10-13-8-6-5-7-9-13/h5-9H,10-12H2,1-4H3

InChI key

RPZAAFUKDPKTKP-UHFFFAOYSA-N

Application

Forms azomethine ylides which readily undergo [3+2] cycloaddition to α,ß-unsaturated esters affording N-benzyl substituted pyrrolidines in good yields.
Reacted in asymmetric 1,3-dipolar cycloadditions in the practical, large-scale synthesis of chiral pyrrolidines.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

150.8 °F - closed cup

Flash Point(C)

66 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 2 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

420697-BULK:
420697-100G:
420697-5G:
420697-1G:
420697-VAR:
420697-25G:

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Certificates of Analysis (COA)

Lot/Batch Number
SHBD4903V
47596DKV
47596DK
47496DK
59496CK

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Synthesis, 2646-2646 (2006)
Kotian, Pravin L.; et al.
Organic Process Research & Development, 9(2), 193-197 (2005)

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