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411124

Sigma-Aldrich

Chlorodicyclohexylborane solution

1 M in hexanes

Synonym(s):

Dicyclohexylboron chloride, Dicyclohexylboryl chloride, Dicyclohexylchloroborane

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About This Item

Linear Formula:
(C6H11)2BCl
CAS Number:
36140-19-9
Molecular Weight:
212.57
Beilstein:
3233942
MDL number:
MFCD00191906
UNSPSC Code:
12352106
PubChem Substance ID:
24865728
NACRES:
NA.22

form

liquid

reaction suitability

reagent type: reductant

concentration

1 M in hexanes

bp

68-69 °C

density

0.752 g/mL at 25 °C

SMILES string

ClB(C1CCCCC1)C2CCCCC2

InChI

1S/C12H22BCl/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h11-12H,1-10H2

InChI key

PBBOKJIYEZCTEH-UHFFFAOYSA-N

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Application

Reactant for:
  • Aldol addition reactions
  • Mukaiyama aldol addition
  • Microwave assisted ring closing metathesis reactions
  • C-alkylation of aromatic aldimines
  • Reversible ketone-ketone aldol reactions
  • Syn- and anti-stereoselective aldol reaction hexenone with aldehydes

Signal Word

Danger

Hazard Classifications

Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 1 Inhalation - STOT SE 3

Target Organs

Central nervous system, Nervous system

Storage Class Code

4.2 - Pyrophoric and self-heating hazardous materials

WGK

WGK 3

Flash Point(F)

10.4 °F - closed cup

Flash Point(C)

-12 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

PRTR

Class I Designated Chemical Substances

FSL

Group 4: Flammable liquids
Type 1 petroleums
Hazardous rank II
Water insoluble liquid

ISHL Indicated Name

Substances Subject to be Indicated Names

ISHL Notified Names

Substances Subject to be Notified Names

JAN Code

411124-100ML:4548173146959
411124-VAR:
411124-BULK:
411124-50ML:4548173146966

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Certificates of Analysis (COA)

Lot/Batch Number
SHBM1437
SHBL8007
SHBJ5997
SHBG2794V
SHBF7177V

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