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308064

Sigma-Aldrich

2-(Trimethylsiloxy)furan

97%

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About This Item

Empirical Formula (Hill Notation):
C7H12O2Si
CAS Number:
61550-02-5
Molecular Weight:
156.25
Beilstein:
1423066
MDL number:
MFCD00011729
UNSPSC Code:
12352100
PubChem Substance ID:
24858645
NACRES:
NA.22

Quality Level

200

Assay

97%

form

liquid

refractive index

n20/D 1.436 (lit.)

bp

34-35 °C/9 mmHg (lit.)

density

0.929 g/mL at 25 °C (lit.)

storage temp.

−20°C

SMILES string

C[Si](C)(C)Oc1ccco1

InChI

1S/C7H12O2Si/c1-10(2,3)9-7-5-4-6-8-7/h4-6H,1-3H3

InChI key

ILBCDLOQMRDXLN-UHFFFAOYSA-N

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Pictograms

FlameExclamation mark
GHS02,GHS07

Signal Word

Danger

Hazard Statements

H225,H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

64.4 °F - closed cup

Flash Point(C)

18 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 1 petroleums
Hazardous rank II
Water insoluble liquid

JAN Code

308064-VAR:
308064-5G:
308064-1G:
308064-INTR:
308064-BULK:

Certificates of Analysis (COA)

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Carlos Silva López et al.
The Journal of organic chemistry, 70(9), 3654-3659 (2005-04-23)
[reaction: see text] A comprehensive scan of the transition state space for the reaction of 2-(trimethylsiloxy)furan and methacrolein (24 combinations) offered a satisfactory explanation of the high like diastereoselectivity obtained experimentally in the Mukaiyama vinylogous aldol reaction of these and

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