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235466

Sigma-Aldrich

1-Vinylimidazole

≥99%

Synonym(s):

1-Ethenyl-1H-imidazole, 1-Ethenylimidazole, 1-Vinyl-1H-imidazole, N-Vinylimidazole

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About This Item

Empirical Formula (Hill Notation):
C5H6N2
CAS Number:
1072-63-5
Molecular Weight:
94.11
Beilstein:
105321
EC Number:
214-012-0
MDL number:
MFCD00005297
UNSPSC Code:
12352005
PubChem Substance ID:
24854105
NACRES:
NA.22

Quality Level

100

Assay

≥99%

form

liquid

refractive index

n20/D 1.533 (lit.)

bp

192-194 °C (lit.)
78-79 °C/13 mmHg (lit.)

density

1.039 g/mL at 25 °C (lit.)

SMILES string

C=Cn1ccnc1

InChI

1S/C5H6N2/c1-2-7-4-3-6-5-7/h2-5H,1H2

InChI key

OSSNTDFYBPYIEC-UHFFFAOYSA-N

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Application

1-Vinylimidazole has been employed:
  • as functional monomer in the synthesis of molecularly imprinted polymers
  • as monomer in the preparation of magnetic-poly(divinylbenzene-1-vinylimidazole) [m-poly(DVB-VIM)] microbeads
  • in the synthesis of novel ion imprinted polyvinylimidazole-silica hybrid copolymer (IIHC)
  • in removal of the vinyl protecting group via isoprene-catalyzed lithiation process

Signal Word

Danger

Hazard Statements

H302 - H318 - H360D

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 1B

Storage Class Code

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 2

Flash Point(F)

183.2 °F - Pensky-Martens closed cup

Flash Point(C)

84 °C - Pensky-Martens closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Tetrahedron, 63, 947-947 (2007)
Bo Mattiasson et al.
Nature protocols, 2(1), 213-220 (2007-04-03)
Affinity precipitation of proteins uses polymers capable of reversible soluble-insoluble transitions in response to small environmental changes (temperature, pH or solvent composition). Here we describe protocols for (i) the synthesis of responsive polymers with specific affinity to target proteins and
Ashok Kumar et al.
Biotechnology and bioengineering, 84(4), 494-503 (2003-10-24)
Metal chelate affinity precipitation (MCAP) has been successfully developed as a simple purification process for proteins that have affinity for metal ions. The present lack of widespread applications for this technique as compared to immobilized metal affinity chromatography (IMAC) may
N Pietruszka et al.
Biotechnology progress, 16(3), 408-415 (2000-06-03)
A new type of polymer, starch-modified by acrylamide, has been developed for application in aqueous two-phase systems (ATPS) for protein separation. Partial hydrolysis and acrylamide modification of starch to different degrees make it suitable for forming ATPS with poly(ethylene glycol)
Bilgen Osman et al.
Applied biochemistry and biotechnology, 168(2), 279-294 (2012-06-28)
Designing an immobilised metal ion affinity process on large-scale demands that a thorough understanding be developed regarding the adsorption behaviour of proteins on metal-loaded gels and the characteristic adsorption parameters to be evaluated. In view of this requirement, interaction of
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