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Safety Information

D216402

Sigma-Aldrich

2,2′-Dipyridylamine

98%

Synonym(s):

bipyam

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About This Item

Empirical Formula (Hill Notation):
C10H9N3
CAS Number:
1202-34-2
Molecular Weight:
171.20
Beilstein:
127131
EC Number:
214-864-3
MDL number:
MFCD00006247
UNSPSC Code:
12352100
PubChem Substance ID:
24893648
NACRES:
NA.22

Quality Level

200

Assay

98%

form

solid

bp

222 °C/50 mmHg (lit.)

mp

90-92 °C (lit.)

SMILES string

N(c1ccccn1)c2ccccn2

InChI

1S/C10H9N3/c1-3-7-11-9(5-1)13-10-6-2-4-8-12-10/h1-8H,(H,11,12,13)

InChI key

HMMPCBAWTWYFLR-UHFFFAOYSA-N

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Application

2,2′-Dipyridylamine (bipyam) can be used:
  • As a bidentate N-donor ligand in the synthesis of various metal complexes.
  • To synthesize Pd-polyoxovanadates, heterogeneous catalyst for the oxidation of benzylic hydrocarbons.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

D216402-5G:
D216402-BULK:
D216402-25G:
D216402-VAR:
D216402-100G:

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Certificates of Analysis (COA)

Lot/Batch Number
BCBQ0269V
BCBP7562V
BCBM2313V
BCBL9451V
BCBL7008V

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John J Allen et al.
Dalton transactions (Cambridge, England : 2003), (5)(5), 878-890 (2009-01-22)
Complexes of the type [Cu(H-dpa)(olefin)]BF4 for ethylene (1), propylene (2), 1-butene (3), 1-hexene (4), 1-octene (5), cis-2-octene (6), trans-2-octene (7), cis-3-octene (8), trans-3-octene (9), 2-norbornylene (10), 1,5-cyclooctadiene (11), styrene (12), cis-stilbene (13), trans-stilbene (14), and Ph2C=CH2 (15) have been prepared
Matthew C Parrott et al.
Journal of the American Chemical Society, 131(8), 2906-2916 (2009-02-26)
A series of aliphatic polyester dendrons, generations 1 through 8, were prepared with a core p-toluenesulfonyl ethyl (TSe) ester as an easily removable protecting group that can be efficiently replaced with a variety of nucleophiles. Using amidation chemistry, a tridentate
Three Pd-decavanadates with a controllable molar ratio of Pd to decavanadate and their heterogeneous aerobic oxidation of benzylic C-H bonds
Huang X, et al.
Dalton Transactions, 47(3), 726-733 (2018)
Faith E Jacobsen et al.
Chembiochem : a European journal of chemical biology, 9(13), 2087-2095 (2008-07-31)
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Manganese (II) complexes of the quinolone family member flumequine: Structure, antimicrobial activity and affinity for albumins and calf-thymus DNA
Barmpa A, et al.
Polyhedron, 145, 166-175 (2018)
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