Skip to Content
Merck
All Photos(2)

Key Documents

View All Documentation

Safety Information

195936

Sigma-Aldrich

3-(Perfluorobutyryl)-(+)-camphor

96%

Synonym(s):

(+)-3-(Heptafluorobutyryl)-(+)-camphor, 3-(Perfluorobutyryl)-D-camphor

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Empirical Formula (Hill Notation):
C14H15F7O2
CAS Number:
51800-99-8
Molecular Weight:
348.26
Beilstein:
2306496
EC Number:
257-430-9
MDL number:
MFCD00064154
UNSPSC Code:
12352115
PubChem Substance ID:
24851726
NACRES:
NA.22

Assay

96%

optical activity

[α]20/D +125°, c = 2.6 in chloroform

refractive index

n20/D 1.421 (lit.)

bp

60-70 °C/0.2 mmHg (lit.)

density

1.218 g/mL at 25 °C (lit.)

functional group

fluoro
ketone

SMILES string

CC1(C)C2CC[C@@]1(C)C(=O)C2C(=O)C(F)(F)C(F)(F)C(F)(F)F

InChI

1S/C14H15F7O2/c1-10(2)6-4-5-11(10,3)8(22)7(6)9(23)12(15,16)13(17,18)14(19,20)21/h6-7H,4-5H2,1-3H3/t6-,7?,11+/m1/s1

InChI key

PEWOESYEGLBLNR-XGLFCGLISA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application

3-(Perfluorobutyryl)-(+)-camphor can be used:
  • As a ligand in the synthesis of chiral europium complex for optoelectronic and photonic applications.
  • As a ligand in the preparation of sodium tetrakis(3-heptafluorobutylryl-(+)-camphorato) Ln(III) complexes applicable as chemical sensors and NMR shift reagents.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

199.4 °F - closed cup

Flash Point(C)

93 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

FSL

Group 4: Flammable liquids
Type 3 petroleums
Hazardous rank III
Water insoluble liquid

JAN Code

195936-1G:
195936-5G:
195936-BULK:
195936-VAR:

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
04920KH
08402LC
03511EE
07327TA
14409DS

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Highly circularly polarized electroluminescence from a chiral europium complex
Zinna F, et al.
Advanced Materials, 27(10), 1791-1795 (2015)
Novel Configurational Structures of Sodium Tetrakis (3-heptafluorobutylryl-(+)-camphorato) Ln (III) Complexes with a Trapped Na+ by Na+?FC Interactions in the Solid State and in Solution
Shirotani D, et al.
Inorganic Chemistry, 45(16), 6111-6113 (2006)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service