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176494

Sigma-Aldrich

Europium tris[3-(trifluoromethylhydroxymethylene)-(+)-camphorate]

Synonym(s):

Eu(facam)3, Eu(tfc)3, Europium(III) tris[3-(trifluoromethylhydroxymethylene)-d-camphorate], Tris(3-trifluoroacetyl-d-camphorato)europium(III), Tris[3-(trifluoromethylhydroxymethylene)-d-camphorato]europium(III)

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About This Item

Empirical Formula (Hill Notation):
C36H42EuF9O6
CAS Number:
34830-11-0
Molecular Weight:
893.66
EC Number:
252-232-9
MDL number:
MFCD00074803
UNSPSC Code:
12352115
PubChem Substance ID:
24850581
NACRES:
NA.22

optical activity

[α]20/D +165°, c = 1% in chloroform (solvent is ethanol free)

technique(s)

NMR: suitable

functional group

fluoro
ketone

SMILES string

CC1(C)C2CCC1(C)C(=O)\C2=C(/O[Eu](O\C(=C3\C4CCC(C)(C3=O)C4(C)C)C(F)(F)F)O\C(=C5\C6CCC(C)(C5=O)C6(C)C)C(F)(F)F)C(F)(F)F

InChI

1S/3C12H15F3O2.Eu/c3*1-10(2)6-4-5-11(10,3)8(16)7(6)9(17)12(13,14)15;/h3*6,17H,4-5H2,1-3H3;/q;;;+3/p-3/b3*9-7-;

InChI key

BWIHMSGCCRUUCZ-NCJHBDPTSA-K

Application

Reactant involved in:
  • The synthesis of europium acetylcamphorate phosphine oxide complexes
  • Reactions with 1,10-N,N′-phenanthroline dioxide derivatives
Optically active NMR shift reagent. Used with Ag(fod) for the enantiomeric resolution of sec-butylisothiouronium chloride.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

176494-BULK:
176494-100MG:
176494-5G:
176494-VAR:
176494-1G:

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Certificates of Analysis (COA)

Lot/Batch Number
BGBC3098V
00418JJ
06315JJ
06615TD
07809JS

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Analytical Chemistry, 59, 562-562 (1987)

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