185892
Ethyl chloroformate
97%
Synonym(s):
Chloroformic acid ethyl ester
About This Item
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vapor density
3.74 (vs air)
Quality Level
vapor pressure
3.42 psi ( 20 °C)
Assay
97%
form
liquid
autoignition temp.
842 °F
refractive index
n20/D 1.395 (lit.)
bp
93 °C (lit.)
mp
−81 °C (lit.)
solubility
alcohol: miscible
benzene: miscible
chloroform: miscible
diethyl ether: miscible
water: insoluble
density
1.135 g/mL at 25 °C (lit.)
functional group
chloro
SMILES string
CCOC(Cl)=O
InChI
1S/C3H5ClO2/c1-2-6-3(4)5/h2H2,1H3
InChI key
RIFGWPKJUGCATF-UHFFFAOYSA-N
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Application
- Ethyl chloroformate was used in the synthesis of nitrile oxides.
- It was used as derivatization reagent to investigate stereochemical conversion of chiral non-steroidal anti-inflammatory drugs during derivatization reaction.
- It was used to develop flexible template strategy for the generation of nanometer-scale templates via dip-pen nanolithography.
- It was used as derivatization reagent in an enantiomeric analysis of amino acids by two-dimensional gas chromatography.
- It was also used with ammonia and cyanuric chloride to convert carboxylic acids to nitriles.
Packaging
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1B
Storage Class Code
3 - Flammable liquids
WGK
WGK 1
Flash Point(F)
60.8 °F
Flash Point(C)
16 °C
Personal Protective Equipment
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
FSL
Group 4: Flammable liquids
Type 1 petroleums
Hazardous rank II
Water insoluble liquid
ISHL Indicated Name
Substances Subject to be Indicated Names
ISHL Notified Names
Substances Subject to be Notified Names
JAN Code
185892-2KG:
185892-BULK:
185892-5ML:
185892-100G:
185892-VAR:
185892-100ML:
185892-5G:
185892-PZ:
185892-500ML:
185892-500G:
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