Skip to Content
Merck
All Photos(1)

Key Documents

Safety Information

152854

Sigma-Aldrich

4-Methoxybenzyloxycarbonyl azide

95%

Synonym(s):

4-Methoxybenzyl azidoformate

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
N3CO2CH2C6H4OCH3
CAS Number:
Molecular Weight:
207.19
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

95%

form

powder

reaction suitability

reaction type: click chemistry

mp

30-32 °C (lit.)

functional group

azide

storage temp.

2-8°C

SMILES string

COc1ccc(COC(=O)N=[N+]=[N-])cc1

InChI

1S/C9H9N3O3/c1-14-8-4-2-7(3-5-8)6-15-9(13)11-12-10/h2-5H,6H2,1H3

InChI key

NQBRFIXRZDTIRQ-UHFFFAOYSA-N

Application

4-Methoxybenzyloxycarbonyl azide was used to prepare N-4-methoxybenzyloxycarbonyl-L-α-aminoadipic acid.

Pictograms

Flame over circleExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Ox. Sol. 2

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

JAN Code

152854-25G:
152854-5G:
152854-VAR:
152854-BULK:


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

J J Usher et al.
The Biochemical journal, 151(3), 729-739 (1975-12-01)
1. Phenoxymethylpenicillin sulphoxide 4-methoxybenzyl ester was labelled with 3H in its 2-beta-methyl group. Its specific radioactivity was 362 mCi/mmol. 2. Removal of the side chain of this compound yielded the corresponding ester of 6-aminopenicillanic acid sulphoxide and coupling of the

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service