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Key Documents

CRM69174

Supelco

Acetochlor

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

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About This Item

Formula empirica (notazione di Hill):
C14H20ClNO2
Numero CAS:
Peso molecolare:
269.77
Beilstein:
2859702
Numero MDL:
Codice UNSPSC:
41116107
NACRES:
NA.24

Grado

certified reference material
TraceCERT®

Livello qualitativo

Nome Commerciale

TraceCERT®

Durata

limited shelf life, expiry date on the label

Produttore/marchio commerciale

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

Formato

neat

Temperatura di conservazione

−20°C

Stringa SMILE

CCOCN(C(=O)CCl)c1c(C)cccc1CC

InChI

1S/C14H20ClNO2/c1-4-12-8-6-7-11(3)14(12)16(10-18-5-2)13(17)9-15/h6-8H,4-5,9-10H2,1-3H3
VTNQPKFIQCLBDU-UHFFFAOYSA-N

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Descrizione generale

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com

Acetochlor belongs to the class of chloroacetamide herbicides, widely used against annual grass and broadleaf weeds. A long-chain fatty acid inhibitor, it is used for pre-emergence and pre-plant control in crops such as maize, peanuts, soybeans, cotton, potatoes, and sugarcane.
According to the Commission Implementing Regulation (EU) No 1372/2011 of 21st December 2011, acetochlor is not approved for use in the European Union (EU) as a plant protection agent, following Regulation (EC) No. 1107/2009. But maximum residue levels of 0.02 mg/kg and 0.05 mg/kg are allowed for its presence in frozen/fresh fruits and tree nuts respectively, according to the EU Reg. No 2015/603.

Applicazioni

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
Acetochlor CRM may also be used as given below:


  • To develop a method for quantifying acetochlor and its metabolites in soybean and corn samples by liquid chromatography-tandem mass spectrometry (LC-MS/MS)
  • QuEChERS-based sample preparation and ultra high-performance liquid chromatographic-tandem mass spectrometric (UHPLC-MS/MS) detection of clomazone and acetochlor residues in soybean samples
  • Analyze a modified QuEChERS-based sample extraction and clean-up method followed by validation using gas chromatography-tandem mass spectrometry (GC-MS/MS analysis) to determine 176 pesticide residues from different chemical classes in fatty matrices
  • Development of a sample treatment method based on ultrasound-assisted solvent extraction and solid-phase extraction clean-up for the quantification of five amide herbicides in fish samples by gas chromatography-electron capture detection (GC-ECD)
  • Simultaneous residue analysis of 42 pesticides in four egg samples using extraction based on the QuEChERS method and determination by UHPLC-MS/MS and GC-MS
  • Analysis of 20 herbicides in human blood samples by liquid-liquid extraction combined with ultra-pressure liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS)

Note legali

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Avvertenze

Warning

Classi di pericolo

Acute Tox. 4 Inhalation - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 - STOT SE 3

Organi bersaglio

Kidney, Respiratory system

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 2


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Certificati d'analisi (COA)

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Development of an LC-MS/MS-based method for determination of acetochlor and its metabolites in crops
Saito-Shida, S, et al.
Journal of food composition and analysis, 108, 104454-104454 (2022)
Simultaneous determination of 42 pesticides and herbicides in chicken eggs by UHPLC-MS/MS and GC-MS using a QuEChERS-based procedure
Li Y, et al
Chromatographia, 79(17), 1165-1175 (2016)
Determination of clomazone and acetochlor residues in soybean (Glycine max (L.) Merr.)
Hussan HNM, et al.
International Journal of Environmental Analytical Chemistry, 101(15), 2503-2509 (2021)
Effects of acetochlor on neurogenesis and behaviour in zebrafish at early developmental stages
Wang H, et al.
Chemosphere, 220, 954-964 (2019)

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