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Key Documents

Altri documenti

S3147

Sigma-Aldrich

5-Sulfosalicylic acid dihydrate

suitable for electrophoresis, ≥99%

Sinonimo/i:

2-Hydroxy-5-sulfobenzoic acid

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About This Item

Formula condensata:
HO3SC6H3-2-(OH)CO2H·2H2O
Numero CAS:
5965-83-3
Peso molecolare:
254.21
Beilstein:
650741
Numero CE:
202-555-6
Numero MDL:
MFCD00149540
Codice UNSPSC:
41105319
ID PubChem:
24899547
NACRES:
NB.22

Saggio

≥99%

Forma fisica

powder or crystals

tecniche

electrophoresis: suitable

Impurezze

≤0.02% Insoluble matter
≤0.05% Salicylic Acid

Punto di fusione

105-110 °C (lit.)

Solubilità

water: soluble 100 mg/mL, clear, colorless

Anioni in tracce

chloride (Cl-): ≤0.001%
sulfate (SO42-): ≤0.035%

Cationi in tracce

Fe: ≤0.001%
heavy metals (as Pb): ≤0.002%

Stringa SMILE

[H]O[H].[H]O[H].OC(=O)c1cc(ccc1O)S(O)(=O)=O

InChI

1S/C7H6O6S.2H2O/c8-6-2-1-4(14(11,12)13)3-5(6)7(9)10;;/h1-3,8H,(H,9,10)(H,11,12,13);2*1H2
BHDKTFQBRFWJKR-UHFFFAOYSA-N

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Descrizione generale

5-Sulfosalicylic acid is a strong acid capable of protonating water. It forms a new theophylline complex, which was investigated by X-ray photoelectron spectroscopy (XPS). It forms 1:1 proton-transfer compounds with the ortho-substituted monocyclic heteroaromatic Lewis bases. Their crystal structures have been studied.

Applicazioni

5-Sulfosalicylic acid (3.5%) in 12% trichloroacetic acid is commonly used as a fixing solution for proteins in agarose and polyacrylamide gels.
5-Sulfosalicylic acid dihydrate may be employed for the quantification of doxorubicin derived from PEGylated liposomal doxorubicin (Doxil) and its major metabolite in human plasma by HPLC. It may be used in the preparation of poly[[tris(di-2-pyridylamine)tris([μ]-5-sulfonatosalicylato)tricopper(II)] trihydrate].

Risultati analitici

Tested for use in fixing solutions for PAGE, SDS-PAGE and IEF.

Pittogrammi

Corrosion
GHS05

Avvertenze

Danger

Indicazioni di pericolo

H314

Classi di pericolo

Eye Dam. 1 - Skin Corr. 1B

Codice della classe di stoccaggio

8A - Combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves

Certificati d'analisi (COA)

Cerca il Certificati d'analisi (COA) digitando il numero di lotto/batch corrispondente. I numeri di lotto o di batch sono stampati sull'etichetta dei prodotti dopo la parola ‘Lotto’ o ‘Batch’.

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Supelco

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David L Chin et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 779(2), 259-269 (2002-10-04)
A high-performance liquid chromatographic method was developed for the quantification of doxorubicin derived from PEGylated liposomal doxorubicin (Doxil) and its major metabolite in human plasma. This method utilizes Triton X-100 to disperse the liposome, followed by a protein precipitation step
Joanna S Stevens et al.
The journal of physical chemistry. B, 114(44), 13961-13969 (2010-10-22)
Recent studies suggested that X-ray photoelectron spectroscopy (XPS) sensitively determines the protonation state of nitrogen functional groups in the solid state, providing a means for distinguishing between co-crystals and salts of organic compounds. Here we describe how a new theophylline
Hydrogen bonding in proton-transfer compounds of 5-sulfosalicylic acid with ortho-substituted monocyclic heteroaromatic Lewis bases.
Smith G, et al.
Journal of Chemical Crystallography, 36(12), 841-849 (2006)
Poly [[tris (di-2-pyridylamine) tris (μ-5-sulfonatosalicylato) tricopper (II)] trihydrate].
Fan SR and Zhu LG.
Acta Crystallographica Section E, Structure Reports Online, 61(1), m174-m176 (2004)
M Vázquez et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 74, 349-359 (2014-12-03)
The mercurial forms [inorganic divalent mercury, Hg(II) and methylmercury, CH3Hg] produce neurological and immune effects as well as hematological and renal alterations. The main route of exposure is through the diet. Consequently, the gastrointestinal mucosa is exposed to these mercurial
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