237213

Sodium nitrite

ACS reagent, ≥97.0%

• Formula condensata: NaNO₂
• Numero CAS: 7632-00-0
• Peso molecolare: 69.00
• Numero CE: 231-555-9
• Numero MDL: MFCD00011118
• Codice UNSPSC: 12352302
• ID PubChem: 329752451
• NACRES: NA.21

Proprietà

• Grado: ACS reagent
• Livello qualitativo: 200
• agenzia: suitable for EPA 300
• Saggio: ≥97.0%
• Forma fisica: powder or crystals
• Temp. autoaccensione: 914 °F
• Impurezze: ≤0.01% insolubles
• Punto di fusione: 271 °C (lit.)
• Anioni in tracce: chloride (Cl^-): ≤0.005%; sulfate (SO₄^2-): ≤0.01%
• Cationi in tracce: Ca: ≤0.01%; Fe: ≤0.001%; K: ≤0.005%; heavy metals (as Pb): ≤0.001%
• Stringa SMILE: [Na+].[O-]N=O
• InChI: 1S/HNO2.Na/c2-1-3;/h(H,2,3);/q;+1/p-1; LPXPTNMVRIOKMN-UHFFFAOYSA-M

Descrizione

Descrizione generale

Sodium nitrite (NaNO₂) is an inorganic compound that is commonly used as a reagent and catalyst in synthetic organic chemistry.

Applicazioni

Co-catalyst for catalytic oxidation of alcohols under aerobic, solvent-free conditions.

Solvent free aerobic oxidation of alcohols with 1-methyl-2-azaadamantane N-oxyl as a recyclable catalyst through phase separation

Sodium nitrite can be used as a reagent in:      

• The Sandmeyer reaction for converting amines into diazo derivatives, and nitration reaction.      
• The oxidative C-C bond formation reaction in the presence of oxygen as the terminal oxidant.      
• The oxidative carbonitration of alkenes in the presence of K₂S₂O₈.

It can also be used as a nitrating agent in organic synthesis. For example, NaNO₂ is used in direct C-H nitration, ipso-nitration, and nitration via transition metal-catalyzed cross-coupling reaction.

Informazioni sulla sicurezza

• Pittogrammi: GHS03,GHS06,GHS09
• Avvertenze: Danger
• Indicazioni di pericolo: H272,H301,H319,H400
• Consigli di prudenza: P210 - P220 - P264 - P273 - P301 + P310 - P305 + P351 + P338
• Classi di pericolo: Acute Tox. 3 Oral - Aquatic Acute 1 - Eye Irrit. 2 - Ox. Sol. 3
• Codice della classe di stoccaggio: 5.1B - Oxidizing hazardous materials
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable