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Merck
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Key Documents

208043

Sigma-Aldrich

Solfuro di sodio

ACS reagent, ≥98.0%

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About This Item

Formula condensata:
Na2S·9H2O
Numero CAS:
Peso molecolare:
240.18
Numero CE:
Numero MDL:
Codice UNSPSC:
12352302
ID PubChem:
NACRES:
NA.21

Grado

ACS reagent

Saggio

≥98.0%

Forma fisica

crystals or chunks

Impiego in reazioni chimiche

reagent type: catalyst
core: sodium

Colore

colorless to slightly yellow

Anioni in tracce

SO32- and S2O32-: ≤0.1%

Cationi in tracce

Fe:, passes test
NH4+: ≤0.005%

Temperatura di conservazione

2-8°C

Stringa SMILE

O.O.O.O.O.O.O.O.O.[Na]S[Na]

InChI

1S/2Na.9H2O.S/h;;9*1H2;
UIINQVYGFKNSPA-UHFFFAOYSA-N

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Descrizione generale

Sodium sulfide nonahydrate participates in the conversion of nitroxides to amines, via reduction.

Applicazioni

Sodium sulfide nonahydrate has been used as a source of H2S, to study the effect of H2S on amyloid fibrils associated with neurodegenerative diseases. It has been used in the preparation of sulfide standards for the quantitative analysis of sulfides in raw wastewater (sewage) samples.
It serves as a catalyst during synthesis of thioamides.
Sodium sulfide nonahydrate has been used as a standard for the quantification of volatile sulfur compounds in cheese samples by gas chromatography. It reacts with 4-(2′-hydroxyaryl)-2-(N,N-dialkylamino)-1,3-dithiolium perchlorates in ethanol at room temperature and boiling ethanol to form 1,3-dithiole-2-thiones and 2′-hydroxyacetophenones, respectively. Sodium sulfide nonahydrate may be used as a reducing agent for the conversion of vic-dibromides to the corresponding olefins via reductive debromination.

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B

Codice della classe di stoccaggio

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable


Certificati d'analisi (COA)

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Preservation and simultaneous analysis of relevant soluble sulfur species in sewage samples
Keller-Lehmann B, et al.
Proceedings of the 2nd International Conference on Intelligent Technologies and Engineering Systems (ICITES2013). Springer International Publishing, 2014., 26 (2006)
Daniel L Priebbenow et al.
Chemical Society reviews, 42(19), 7870-7880 (2013-06-25)
The Willgerodt-Kindler reaction has, in recent years, received limited attention and application in synthetic organic chemistry. With the advent of new technology such as microwave-assisted heating, several new, high-yielding, practical, and more environmentally friendly reaction protocols have been developed. This
Reduction of nitroxides to amines by sodium sulfide.
Kornblum N and Pinnick HW.
The Journal of Organic Chemistry, 37(12), 2050-2051 (1972)
Manuel F Rosario-Alomar et al.
The journal of physical chemistry. B, 119(4), 1265-1274 (2014-12-30)
Amyloid fibrils are large aggregates of misfolded proteins, which are often associated with various neurodegenerative diseases such as Alzheimer's, Parkinson's, Huntington's, and vascular dementia. The amount of hydrogen sulfide (H2S) is known to be significantly reduced in the brain tissue
Reaction of 4-(2'-Hydroxyaryl)-1, 3-dithiolium Salts with Sodium Sulfide. A Selective Synthesis of 2'-Hydroxyacetophenones.
Birsa ML.
Synthetic Communications, 33(17), 3071-3076 (2003)

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