00375

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl

purum, ≥98.0% (HPLC)

• Formula empirica (notazione di Hill): C₁₁H₂₁N₂O₂
• Numero CAS: 14691-89-5
• Peso molecolare: 213.30
• Beilstein: 3546225
• Numero CE: 423-840-3
• Numero MDL: MFCD00043593
• Codice UNSPSC: 12352005
• ID PubChem: 329747053
• NACRES: NA.22

Proprietà

• Grado: purum
• Livello qualitativo: 200
• Saggio: ≥98.0% (HPLC)
• Punteggio alternativa più verde: old score: 9; new score: 8; Find out more about DOZN™ Scoring
• Caratteristiche più verdi: Waste Prevention; Safer Solvents and Auxiliaries; Inherently Safer Chemistry for Accident Prevention; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Punto di fusione: 143-145 °C (lit.); 143-146 °C
• Gruppo funzionale: amide
• Categoria alternativa più verde: , Re-engineered
• Temperatura di conservazione: 2-8°C
• Stringa SMILE: CC(=O)NC1CC(C)(C)N([O])C(C)(C)C1
• InChI: 1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14); UXBLSWOMIHTQPH-UHFFFAOYSA-N

Descrizione

Descrizione generale

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by ¹H, ¹³C and ¹⁵N NMR spectral data.

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives . This product belongs to category of Re-engineered products, showing key improvements in Green Chemistry Principles “Waste Prevention”, “Safer Solvents and Auxiliaries” and “Inherently Safer Chemistry for Accident Prevention”. Click here to view its DOZN scorecard.

Applicazioni

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be employed as model nitroxyl radical to study its reaction with thiophosgene. Reaction afforded 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-1-hydroxypiperidine as major products.

Altre note

New oxidant for the mild oxidation of alcohols to carbonyls

Informazioni sulla sicurezza

• Pittogrammi: GHS07
• Avvertenze: Warning
• Indicazioni di pericolo: H302
• Consigli di prudenza: P264 - P270 - P301 + P312 - P501
• Classi di pericolo: Acute Tox. 4 Oral
• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 1
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable
• Dispositivi di protezione individuale: dust mask type N95 (US), Eyeshields, Gloves