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D87589

Sigma-Aldrich

Diethyl aminomalonate hydrochloride

98%

Sinonimo/i:

Aminomalonic acid diethyl ester hydrochloride

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About This Item

Formula condensata:
NH2CH2(COOC2H5)2 · HCl
Numero CAS:
13433-00-6
Peso molecolare:
211.64
Beilstein:
3568037
Numero CE:
236-556-8
Numero MDL:
MFCD00012510
Codice UNSPSC:
12352100
ID PubChem:
24894222
NACRES:
NA.22

Saggio

98%

Forma fisica

crystals

Punto di fusione

165-170 °C (dec.) (lit.)

Stringa SMILE

Cl.CCOC(=O)C(N)C(=O)OCC

InChI

1S/C7H13NO4.ClH/c1-3-11-6(9)5(8)7(10)12-4-2;/h5H,3-4,8H2,1-2H3;1H
GLFVNTDRBTZJIY-UHFFFAOYSA-N

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Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves

Certificati d'analisi (COA)

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Sigma-Aldrich

G1763

β-Glutamic acid

Diethyl malonate ReagentPlus®, 99%

Sigma-Aldrich

D97754

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Glyoxal solution 40 wt. % in H2O

Sigma-Aldrich

128465

Glyoxal solution

C M Metzler et al.
Biochemistry, 27(13), 4923-4933 (1988-06-28)
To establish the state of protonation of quinonoid species formed nonenzymically from pyridoxal phosphate (PLP) and diethyl aminomalonate, we have studied absorption spectra of the rapidly established steady-state mixture of species. We have evaluated the formation constant and the spectrum
Seiichi Ohta et al.
Molecular pharmaceutics, 14(9), 3105-3113 (2017-08-15)
Intraperitoneal administration of chemotherapeutics is expected for the treatment of peritoneally disseminated gastric cancer because of poor migration of the drugs from the systemic circulation to the peritoneal cavity. In this study, for intraperitoneal delivery of cisplatin (CDDP), we developed
Reaction control in the organocatalytic asymmetric one-pot, three-component reaction of aldehydes, diethyl alpha-aminomalonate and nitroalkenes: toward diversity-oriented synthesis.
Yan-Kai Liu et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(32), 9873-9877 (2008-10-04)
F Hughes et al.
Organic letters, 3(18), 2911-2914 (2001-09-01)
[reaction: see text]. Nitrogen-containing tethered diacids, easily prepared by reductive alkylation of diethyl aminomalonate or ethyl cyanoglycinate, undergo double Michael reactions with 3-butyn-2-one to give highly functionalized and substituted piperidines (pipecolic acid derivatives) with surprisingly high stereoselectivity. The heterocyclic double
Charles M Blazey et al.
The Journal of organic chemistry, 67(1), 298-300 (2002-01-05)
The azomethine ylide derived from the condensation of diethyl aminomalonate with paraformaldehyde undergoes 1,3-dipolar cycloadditions with acrylate and propiolate derivatives. Contrary to a previous report, these reactions yield mixtures of regioisomers generally favoring the 2,2,3-trisubstituted product. However, the relative quantity

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