ALD00627

6-(2-(5-chloropyridin-2-yl)-1-phenylpropan-2-yl)pyridin-2-ol

• Formula empirica (notazione di Hill): C₁₉H₁₇ClN₂O
• Peso molecolare: 324.80
• Codice UNSPSC: 12352100
• NACRES: NA.21

Proprietà

• Forma fisica: powder
• Livello qualitativo: 100
• Punto di fusione: 188-189 °C
• Temperatura di conservazione: −20°C

Descrizione

Applicazioni

This ligand was developed by the Yu lab to enable the Pd-catalyzed dehydrogenation of aliphatic carboxylic acids through a typically challenging activation of the β-methylene C-H bond. This method is chemoselective to carboxylic acids even in the presence of other enolizable functional groups, and may also viably utilize molecular oxygen as the terminal oxidant for the transformation.

Altre note

Ligand-controlled divergent dehydrogenative reactions of carboxylic acids via C–H activation

A tautomeric ligand enables directed C-H hydroxylation with molecular oxygen

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable