938726

ImPy-Dipop-Dipp

• Sinonimo/i: 5-(2,6-diisopropoxyphenyl)-2-(2,6-diisopropylphenyl)imidazo[1,5-a]pyridin-2-ium chloride
• Formula empirica (notazione di Hill): C₃₁H₃₉ClN₂O₂
• Numero CAS: 2983007-49-2
• Peso molecolare: 507.11
• Codice UNSPSC: 12352100

Proprietà

• Stato: powder
• Livello qualitativo: 100
• Impiego in reazioni chimiche: reaction type: Cross Couplings
• Colore: white
• Stringa SMILE: CC(C1=CC=CC(C(C)C)=C1[N+]2=CN3C(C4=C(OC(C)C)C=CC=C4OC(C)C)=CC=CC3=C2)C.[Cl-]
• InChI: 1S/C31H39N2O2.ClH/c1-20(2)25-13-10-14-26(21(3)4)31(25)32-18-24-12-9-15-27(33(24)19-32)30-28(34-22(5)6)16-11-17-29(30)35-23(7)8;/h9-23H,1-8H3;1H/q+1;/p-1; XMDMIAJKGFBECK-UHFFFAOYSA-M

Descrizione

Descrizione generale

ImPy-Dipop-Dipp is an NHC precursor developed in the Szostak group. The ligand is useful in a range of catalytic transformations, and is particulary well suited to the following: Suzuki-Miyaura cross-coupling of aryl mesylates and tosylates, Suzuki–Miyaura cross-coupling of nitroarenes (Ar–NO₂), Buchwald-Hartwig amination of alkyl sulfoxides

Applicazioni

Suzuki-Miyaura cross-coupling of aryl mesylates and tosylates Suzuki–Miyaura cross-coupling of nitroarenes (Ar–NO₂) or aryl sulfamates Buchwald-Hartwig amination of alkyl sulfoxides or aryl sulfamates

Caratteristiche e vantaggi

ImPy-Dipop-Dipp is an asymmetric NHC ligand precursor. It forms air-and moisture stable complexes with transition metals and is particulary effective in palladium catalyzed cross-coupling reactions.

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable