746339

Dichlorotriphenylphosphine[bis(2-(ethylthio)ethyl)amine]ruthenium(II)

97%

• Sinonimo/i: Ru-SNS catalyst
• Formula empirica (notazione di Hill): C₂₆H₃₄Cl₂NPRuS₂
• Numero CAS: 1462397-86-9
• Peso molecolare: 627.63
• Numero MDL: MFCD26960799
• Codice UNSPSC: 12161600
• ID PubChem: 329765759
• NACRES: NA.22

Proprietà

• Livello qualitativo: 100
• Saggio: 97%
• Forma fisica: solid
• Impiego in reazioni chimiche: core: ruthenium; reagent type: catalyst
• Caratteristiche più verdi: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Punto di fusione: 300-310 °C
• Categoria alternativa più verde: Aligned,
• Stringa SMILE: CCSCCN([H])CCSCC.Cl[Ru]Cl.P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
• InChI: 1S/C18H15P.C8H19NS2.2ClH.Ru/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-3-10-7-5-9-6-8-11-4-2;;;/h1-15H;9H,3-8H2,1-2H3;2*1H;/q;;;;+2/p-2; ZQGMNGJIEYHKBR-UHFFFAOYSA-L

Descrizione

Descrizione generale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Applicazioni

Catalyst for hydrogenation of esters to alcohols. Greener alternative to stoichiometric hydride reagents.

Replacing Phosphorus with Sulfur for the Efficient Hydrogenation of Esters

Catalyst for the hydrogenation of esters to alcohols.

Altre note

"The mer-SNS complexes form isomers in solution. This is due to the different arrangements of the SEt groups relative to the SNS ligand plane. Two of the isomers have eclipsed SEt groups (arranged on one side of the SNS plane), and the third isomer has staggered SEt groups (occupying the opposite sides of the SNS plane)."

Note legali

This Product is licensed from GreenCentre Canada for non-commercial, research use only. Please contact GreenCentre Canada for information regarding commercial use of Product.

Informazioni sulla sicurezza

• Pittogrammi: GHS06
• Avvertenze: Danger
• Indicazioni di pericolo: H302 + H312,H331
• Consigli di prudenza: P280 - P301 + P312 + P330 - P302 + P352 + P312 - P304 + P340 + P311
• Classi di pericolo: Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral
• Codice della classe di stoccaggio: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable