Passa al contenuto
Merck
Tutte le immagini(1)

Documenti fondamentali

742945

Sigma-Aldrich

TurboBeads™ TEMPO

≥99%

Sinonimo/i:

Nano particles, magnetic, TEMPO functionalized

Autenticatiper visualizzare i prezzi riservati alla tua organizzazione & contrattuali
Tutte le immagini(1)

About This Item

Codice UNSPSC:
12352128
NACRES:
NA.22

Nome Commerciale

TurboBeads™

Saggio

≥99%

Stato

powder

Composizione

carbon content, ≤14 wt. %

Impiego in reazioni chimiche

reaction type: solution phase peptide synthesis
reactivity: alcohol reactive

Grado di funzionalizzazione

≥0.1 mmol/g loading (TEMPO)

Magnetizzazione

≥120 emu/g, mass saturation

Area superficiale

≥15 m2/g

Diametro medio

≤50 nm

Compatibilità

conforms to structure for Infrared spectrum

Applicazioni

Recyclable TEMPO (2,2,6,6-tetramethylpiperidine 1-oxyl radical)-coated nanoparticles have been prepared by the immobilization of TEMPO on iron oxide (Fe3O4) superparamagnetic nanoparticles.

Confezionamento

Bottomless glass bottle. Contents are inside inserted fused cone.

Risultati analitici

Proof of identity: metallic cobalt identity from XRD

air-stability:
weight gain in air at 400°C >20 wt.%
weight gain in air at 100°C <3 wt.%

Note legali

TurboBeads is a trademark of TurboBeads LLC

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Scegli una delle versioni più recenti:

Certificati d'analisi (COA)

Lot/Batch Number
BCBK1100V
BCBK1100

Non trovi la versione di tuo interesse?

Se hai bisogno di una versione specifica, puoi cercare il certificato tramite il numero di lotto.

Cerca un COA

Possiedi già questo prodotto?

I documenti relativi ai prodotti acquistati recentemente sono disponibili nell’Archivio dei documenti.

Visita l’Archivio dei documenti

Alexander K Tucker-Schwartz et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(42), 12718-12726 (2010-09-21)
The organic oxidant TEMPO (2,2,4,4-tetramethylpiperdine-1-oxyl) was immobilized on iron oxide (Fe(3)O(4)) superparamagnetic nanoparticles by employing strong metal-oxide chelating phosphonates and azide/alkyne "click" chemistry. This simple preparation yields recyclable TEMPO-coated nanoparticles with good TEMPO loadings. They have excellent magnetic response and
Jacinto Sá et al.
Nanoscale, 5(18), 8462-8465 (2013-07-12)
Non-magnetic Pt catalysts, supported on carbon coated magnetic Co nanoparticles, changed catalytic performance in the presence of an external magnetic field. This behavior relates to an electronic change of Pt induced by a localized magnetic field, which modifies the CO
Quirin M Kainz et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(30), 10038-10045 (2013-06-19)
Unprecedented magnetic borohydride exchange (mBER), magnetic Wang aldehyde (mWang) and magnetic amine resins were prepared from highly magnetic polymer-coated cobalt or iron nanoparticles. Microwave irradiation was used to obtain excellent degrees of functionalization (>95 %) and loadings (up to 3.0 mmol  g(-1))
Hideya Kawasaki et al.
Analytical chemistry, 84(21), 9268-9275 (2012-09-29)
Graphene-coated cobalt nanoparticles surface-functionalized with benzylamine groups (CoC-NH(2) nanomagnets) were shown to effectively enrich analytes for surface-assisted laser desorption/ionization mass spectrometry (affinity SALDI-MS) analysis. These CoC-NH(2) nanomagnets are highly suited for use with affinity SALDI-MS because their mean diameter of
Inge K Herrmann et al.
Nanoscale, 5(18), 8718-8723 (2013-08-01)
In a number of clinical conditions such as intoxication, bacteraemia or autoimmune diseases the removal of the disease-causing factor from blood would be the most direct cure. However, physicochemical characteristics of the target compounds limit the applicability of classical filtration
Visualizza tutti i documenti correlati

Articoli

TEMPO Catalyzed Oxidations

TEMPO (2,2,6,6-Tetramethylpiperidinyloxy or 2,2,6,6-Tetramethylpiperidine 1-oxyl) and its derivatives are stable nitroxy radicals used as catalysts in organic oxidation reactions. TEMPO was discovered by Lebedev and Kazarnovskii in 1960. The stable free radical nature of TEMPO is due to the presence of bulky substituent groups, which hinder the reaction of the free radical with other molecules.

Il team dei nostri ricercatori vanta grande esperienza in tutte le aree della ricerca quali Life Science, scienza dei materiali, sintesi chimica, cromatografia, discipline analitiche, ecc..

Contatta l'Assistenza Tecnica.