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Documenti fondamentali

517453

Sigma-Aldrich

Copper(II) acetate

greener alternative

powder, 99.99% trace metals basis

Sinonimo/i:

Cupric acetate

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About This Item

Formula condensata:
Cu(CO2CH3)2
Numero CAS:
Peso molecolare:
181.63
Beilstein:
3595638
Numero CE:
Numero MDL:
Codice UNSPSC:
12352103
ID PubChem:
NACRES:
NA.23

Densità del vapore

6.9 (vs air)

Saggio

99.99% trace metals basis

Stato

powder

Impiego in reazioni chimiche

core: copper

Caratteristiche più verdi

Catalysis
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sustainability

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Categoria alternativa più verde

Stringa SMILE

CC(=O)O[Cu]OC(C)=O

InChI

1S/2C2H4O2.Cu/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
OPQARKPSCNTWTJ-UHFFFAOYSA-L

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Descrizione generale

Copper acetate (Cu (OAc)2) occurs in dimeric structure in solid state and in non-aqueous solution. Anhydrous Cu (OAc)2 may be manufactured by heating or refluxing the monohydrate Cu (OAc)2 at 90oC and then washing the insoluble product with diethyl ether.
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Applicazioni

Copper acetate forms complexes which may be used in biochemical reactions such as; DNA extraction, binding ribose hydroxyls of purine and pyrimidine nucleosides. A study has shown Cu (OAc)2 to fix and remove tannins in samples from Pyrus yielding high quality DNA. The complexes have been studied for anticancer, anti-bacterial and antifungal activities.

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Skin Corr. 1B

Codice della classe di stoccaggio

8B - Non-combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

does not flash

Punto d’infiammabilità (°C)

does not flash

Dispositivi di protezione individuale

dust mask type N95 (US), Eyeshields, Gloves


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Certificati d'analisi (COA)

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Benzoin for synthesis

Sigma-Aldrich

8.01776

Benzoin

Benzoin purified by sublimation, ≥99.5%

Sigma-Aldrich

399396

Benzoin

Stereoselective differentiation between ribonucleosides and deoxynucleosides by reaction with the copper(II) acetate dimer.
N A Berger et al.
Nature: New biology, 239(95), 237-240 (1972-10-25)
Quantitative densitometric thin-layer chromatography of lipids using copper acetate reagent.
M E Fewster et al.
Journal of chromatography, 43(1), 120-126 (1969-08-05)
Michael Devereux et al.
Journal of inorganic biochemistry, 98(6), 1023-1031 (2004-05-20)
Thiabendazole (TBZH) reacts with iron(III) nitrate causing protonation of the ligand to yield the nitrate salt [TBZH(2)NO(3)] (1). Reaction of TBZH with copper(II) acetate results in the deprotonation of the ligand yielding [Cu(TBZ)2.(H2O)2] (2). Reactions of TBZH with the chloride
Manpreet Kaur et al.
Nanoscale research letters, 13(1), 182-182 (2018-06-20)
Here, we report efficient composition-tunable Cu-doped ZnInS/ZnS (core and core/shell) colloidal nanocrystals (CNCs) synthesized by using a colloidal non-injection method. The initial precursors for the synthesis were used in oleate form rather than in powder form, resulting in a nearly
Hanmei Zheng et al.
The Journal of organic chemistry, 74(2), 943-945 (2008-12-11)
A novel copper-catalyzed protocol for the synthesis of carbinol derivatives has been developed. In the presence of copper(II) acetate and dppf, carbinol derivatives were prepared by the addition of arylboronic acids to aromatic aldehydes in good to excellent yields. Moreover

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