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232750

Sigma-Aldrich

1-Bromo-2-chloroethane

98%

Sinonimo/i:

Ethylene bromochloride, Ethylene chlorobromide

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About This Item

Formula condensata:
ClCH2CH2Br
Numero CAS:
107-04-0
Peso molecolare:
143.41
Beilstein:
605265
Numero CE:
203-456-0
Numero MDL:
MFCD00000962
Codice UNSPSC:
12352100
ID PubChem:
24853925
NACRES:
NA.22

Saggio

98%

Forma fisica

liquid

Indice di rifrazione

n20/D 1.488 (lit.)

P. eboll.

106-107 °C (lit.)

Punto di fusione

−18-−14 °C (lit.)

Solubilità

water: soluble

Densità

1.723 g/mL at 25 °C (lit.)

Gruppo funzionale

bromo

Stringa SMILE

ClCCBr

InChI

1S/C2H4BrCl/c3-1-2-4/h1-2H2
IBYHHJPAARCAIE-UHFFFAOYSA-N

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Descrizione generale

Dissociative double ionization and multi-photon ionization of 1-bromo-2-chloroethane (BCE) irradiated by the 800nm femtosecond laser field has been investigated by dc-slice imaging technology. Conformational properties of BCE in several zeolites such as silicalite-1, siliceous Y, Na-Y and zeolite L have been investigated by FT-Raman spectroscopy.

Applicazioni

1-Bromo-2-chloroethane was used in regio- and diastereoselective synthesis of 2-alkylidenetetrahydrofurans.

Pittogrammi

Skull and crossbonesHealth hazard
GHS06,GHS08

Avvertenze

Danger

Indicazioni di pericolo

H301,H312 + H332,H315,H335,H350

Classi di pericolo

Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Carc. 1B - Skin Irrit. 2 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
BCCF3165
BCCC1146
BCBQ8054V
BCBT8089
BCBP6859V

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Sigma-Aldrich

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2-Chloroethanol 99%

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P Langer et al.
The Journal of organic chemistry, 66(18), 6057-6063 (2001-09-01)
The domino C,O-cyclodialkylation reaction of dilithiated 1,3-dicarbonyl compounds with 1,4-dibromo-2-butene resulted in regio- and diastereoselective formation of 2-alkylidene-5-vinyltetrahydrofurans. The cyclization of 1,3-dicarbonyl dianions with 1-bromo-2-chloroethane regio- and diastereoselectively afforded 2-alkylidenetetrahydrofurans under thermodynamic reaction control.
Yan Yang et al.
The Journal of chemical physics, 135(6), 064303-064303 (2011-08-17)
The dissociative double ionization and multi-photon ionization of 1-bromo-2-chloroethane (BCE) irradiated by the 800 nm femtosecond laser field have been investigated by dc-slice imaging technology. The charged parent ion ratio [BCE(2+)]/[BCE(+)] was measured, and the corresponding ionization process including non-sequential
R D Storer et al.
Carcinogenesis, 4(11), 1491-1494 (1983-11-01)
Hepatic DNA damage was demonstrated by alkaline DNA unwinding/hydroxylapatite batch chromatography in male B6C3F1 mice treated with non-necrogenic doses of 1,2-dichloroethane, 1-bromo-2-chloroethane, and 1,2-dibromoethane. Intraperitoneal administration of 0.5 mmol/kg of 1-bromo-2-chloroethane and 1,2-dibromoethane produced similar levels of DNA damage. A
J Plenge et al.
Physical chemistry chemical physics : PCCP, 13(19), 8705-8714 (2011-03-29)
We report on the coherent control of the ultrafast ionization and fragmentation dynamics of the bromochloroalkanes C(2)H(4)BrCl and C(3)H(6)BrCl using shaped femtosecond laser pulses. In closed-loop control experiments on bromochloropropane (C(3)H(6)BrCl) the fragment ion yields of CH(2)Cl(+), CH(2)Br(+), and C(3)H(3)(+)
Haiyan Wang et al.
Langmuir : the ACS journal of surfaces and colloids, 25(14), 8042-8050 (2009-04-21)
The conformational properties of 1-bromo-2-chloroethane (BCE) in several representative zeolites including silicalite-1, siliceous Y (Si-Y), Na-Y, and zeolite L have been investigated by FT-Raman spectroscopy in combination with thermogravimetric analysis. The results indicate that the conformational and dynamic behavior of
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