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230022

Sigma-Aldrich

Zinc bromide

99.999% trace metals basis

Sinonimo/i:

Zinc dibromide

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About This Item

Formula condensata:
ZnBr2
Numero CAS:
7699-45-8
Peso molecolare:
225.20
Numero CE:
231-718-4
Numero MDL:
MFCD00011294
Codice UNSPSC:
12352302
eCl@ss:
38150410
ID PubChem:
24853770
NACRES:
NA.23

Saggio

99.999% trace metals basis

Forma fisica

powder and chunks

Impiego in reazioni chimiche

reagent type: catalyst
core: zinc

Impurezze

≤15.0 ppm Trace Metal Analysis

P. eboll.

~670 °C/1 atm (lit.)

Punto di fusione

394 °C (lit.)

Solubilità

diethyl ether: slightly soluble(lit.)
ethanol: very soluble(lit.)

Stringa SMILE

Br[Zn]Br

InChI

1S/2BrH.Zn/h2*1H;/q;;+2/p-2
VNDYJBBGRKZCSX-UHFFFAOYSA-L

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Applicazioni

Zinc bromide supported on silica or montmorillonite can be used as a selective catalyst for the bromination of aromatic substrates.

It can be used as starting material to prepare poly(ethylene oxide)/ zinc salt systems, which can be used as polymer electrolytes.

Itcan also be used to prepare ZnO nanoparticles.

Avvertenze

Danger

Indicazioni di pericolo

H302,H314,H317,H411

Classi di pericolo

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1

Codice della classe di stoccaggio

8A - Combustible corrosive hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificati d'analisi (COA)

Lot/Batch Number
MKBZ4291V
MKBX3201V
MKBR9650V
MKBR3677V
MKBL5123V

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Franz, A.K. Woerpel, K.A.
Journal of the American Chemical Society, 121, 949-949 (1999)
Erik Lundberg et al.
Journal of structural biology, 155(3), 445-457 (2006-05-26)
The transthyretin-related protein (TRP) family comprises proteins predicted to be structurally related to the homotetrameric transport protein transthyretin (TTR). The function of TRPs is not yet fully established, but recent data suggest that they are involved in purine catabolism. We
Yejian Han et al.
Organic letters, 13(4), 588-591 (2011-01-12)
An efficient and versatile ZnBr(2)-catalyzed Diels-Alder/carbocyclization cascade reaction has been developed for construction of highly functionalized cis-hydrindanes (70-96% yields with high diastereoselectivity), and it has been successfully utilized in the synthesis of the aglycon of dendronobiloside A.
Ruixue Deng et al.
Organic letters, 9(25), 5207-5210 (2007-11-10)
A number of indenes have been prepared in good yields by treating o-bromobenzyl zinc bromide 1 with various terminal and internal alkynes in the presence of a nickel catalyst. The nickel-catalyzed carboannulation reaction was successfully extended to the synthesis of
S Takeda et al.
Chemical & pharmaceutical bulletin, 48(7), 1097-1100 (2000-08-03)
The alpha,alpha-gem-difluorination of 2',4'-difluoro-alpha-(methylthio)acetophenone (1a) with N-fluoropyridinium salts gave 2',4',alpha,alpha-tetrafluoro-alpha-(methylthio)acetophenone (3a). This reaction was accelerated by the addition of zinc chloride, zinc bromide or anhydrous iron(III) chloride, and higher yields than the reaction without additives were obtained. The gem-difluorination reaction
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