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226637

Sigma-Aldrich

Butyl nitrite

95%

Sinonimo/i:

n-Butyl nitrite

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About This Item

Formula condensata:
CH3(CH2)3ONO
Numero CAS:
544-16-1
Peso molecolare:
103.12
Beilstein:
1701036
Numero CE:
208-862-1
Numero MDL:
MFCD00002058
Codice UNSPSC:
12352100
ID PubChem:
24853580
NACRES:
NA.22

Tensione di vapore

760 mmHg ( 78 °C)

Saggio

95%

Stato

liquid

Indice di rifrazione

n20/D 1.376 (lit.)

P. ebollizione

78 °C (lit.)

Solubilità

alcohol: miscible(lit.)
diethyl ether: miscible(lit.)

Densità

0.882 g/mL at 25 °C (lit.)

Gruppo funzionale

O-nitroso
nitroso

Temperatura di conservazione

2-8°C

Stringa SMILE

CCCCON=O

InChI

1S/C4H9NO2/c1-2-3-4-7-5-6/h2-4H2,1H3
JQJPBYFTQAANLE-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

The photodissociation dynamics of butyl nitrite was studied using time-resolved Fourier transform infrared (TR-FTIR) emission spectroscopy. The effects of butyl nitrite on methyl cobalamin and 5-methyl tetrahydrofolate were studied.

Pittogrammi

FlameSkull and crossbones
GHS02,GHS06

Avvertenze

Danger

Indicazioni di pericolo

H225,H301,H330

Classi di pericolo

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

8.6 °F - closed cup

Punto d’infiammabilità (°C)

-13 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
MKCQ5122
MKCN7719
MKCN5365
MKCM2877
MKCL4353

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G R Newell et al.
Pharmacotherapy, 4(5), 284-291 (1984-09-01)
Volatile nitrite in the form of amyl nitrite was used for 100 years for the treatment of angina pectoris. In spite of recognized toxicity, its use in this form was considered safe. During the 1960s prescriptions were not required for
J D Osterloh et al.
Journal of pharmaceutical sciences, 74(7), 780-782 (1985-07-01)
The uptake of butyl nitrite by rats (500 g, one rat/chamber) was determined over a 5-min exposure period. About 44% of the starting amount (771-3855 ppm) of n-butyl nitrite was consumed in 5 min. Three rats per exposure concentration were
Tsuyoshi Taniguchi et al.
Chemical communications (Cambridge, England), 49(22), 2198-2200 (2013-02-12)
A method for direct functionalization of three positions including an unactivated C-H bond of aliphatic alkenes using tert-butyl nitrite and molecular oxygen to give γ-lactols has been developed. The present reaction proceeds through a sequence of radical processes involving oxynitration
Dipankar Koley et al.
Organic letters, 11(18), 4172-4175 (2009-08-25)
tert-Butyl nitrite was identified as a safe and chemoselective nitrating agent that provides preferentially mononitro derivatives of phenolic substrates in the presence of potentially competitive functional groups. On the basis of our control experiments, we propose that the reaction proceeds
E Roth et al.
American journal of hematology, 20(2), 153-159 (1985-10-01)
The use of volatile butylnitrite in place of sodium nitrite for the in vitro production of methemoglobin was explored in studies of G6PD-deficient red cells and for measurements of the red cell methemoglobin reductase activity. It was found that butylnitrite
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