222380

Allylpalladium(II) chloride dimer

98%

• Sinonimo/i: Bis((η3-allyl)(chloro)palladium), Di-ο-allyldi-μ-chlorodipalladium, [PdCl(C₃H₅)]₂
• Formula empirica (notazione di Hill): C₆H₁₀Cl₂Pd₂
• Numero CAS: 12012-95-2
• Peso molecolare: 365.89
• Beilstein: 4124623
• Numero CE: 234-579-8
• Numero MDL: MFCD00044874
• Codice UNSPSC: 12161600
• ID PubChem: 24853328
• NACRES: NA.22

Proprietà

• Livello qualitativo: 200
• Saggio: 98%
• Stato: solid
• Impiego in reazioni chimiche: core: palladium; reaction type: Cross Couplings; reagent type: catalyst; reaction type: C-H Activation
• Caratteristiche più verdi: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Categoria alternativa più verde: , Aligned
• Temperatura di conservazione: 2-8°C
• Stringa SMILE: Cl[Pd]CC=C.Cl[Pd]CC=C
• InChI: 1S/2C3H5.2ClH.2Pd/c2*1-3-2;;;;/h2*3H,1-2H2;2*1H;;/q;;;;2*+1/p-2; TWKVUTXHANJYGH-UHFFFAOYSA-L

Descrizione

Descrizione generale

Allylpalladium(II) chloride dimer is employed as catalyst in Heck reaction. It also participates as catalyst in the tandem nucleophilic allylation-alkoxyallylation reaction of the alkynylaldehydes with allyl chloride and allyltributylstannane.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Applicazioni

Application Guide for Palladium Catalyzed Cross-Coupling Reactions

Allylpalladium(II) chloride dimer has been employed for the following studies:

• Synthesis of cationic palladium cataysts, used in the microwave-assisted Heck arylation.
• Synthesis of N-heterocyclic carbene-palladium-η³-allyl chloride complexes, which are efficient catalyst for the Suzuki-Miyaura cross-coupling of aryl bromides and activated aryl chlorides.
• Synthesis of 1,4-diallyl-1,2-dihydroisoquinolines.
• As catalyst for greener Buchwald-Hartwig coupling in TPGS-750-M.

On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors

Informazioni sulla sicurezza

• Pittogrammi: GHS07
• Avvertenze: Warning
• Indicazioni di pericolo: H315
• Consigli di prudenza: P264 - P280 - P302 + P352 - P332 + P313 - P362 + P364
• Classi di pericolo: Skin Irrit. 2
• Codice della classe di stoccaggio: 11 - Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Dispositivi di protezione individuale: dust mask type N95 (US), Eyeshields, Faceshields, Gloves