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179760

Sigma-Aldrich

2-Acetylcyclohexanone

97%

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About This Item

Formula condensata:
CH3COC6H9(=O)
Numero CAS:
874-23-7
Peso molecolare:
140.18
Beilstein:
1858621
Numero CE:
212-858-5
Numero MDL:
MFCD00001633
Codice UNSPSC:
12352100
ID PubChem:
24850652
NACRES:
NA.22

Saggio

97%

Forma fisica

liquid

Indice di rifrazione

n20/D 1.509 (lit.)

P. eboll.

111-112 °C/18 mmHg (lit.)

Densità

1.078 g/mL at 25 °C (lit.)

Stringa SMILE

CC(=O)C1CCCCC1=O

InChI

1S/C8H12O2/c1-6(9)7-4-2-3-5-8(7)10/h7H,2-5H2,1H3
OEKATORRSPXJHE-UHFFFAOYSA-N

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Descrizione generale

The keto-enol tautomerism of 2-acetylcyclohexanone (ACHE) in water was studied.

Applicazioni

2-Acetylcyclohexanone was used in the synthesis of anilinoethanolamines.

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

174.2 °F - closed cup

Punto d’infiammabilità (°C)

79 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Certificati d'analisi (COA)

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Sigma-Aldrich

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Sigma-Aldrich

E20004

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Emilia Iglesias
The Journal of organic chemistry, 68(7), 2680-2688 (2003-03-29)
The keto-enol tautomerism of 2-acetylcyclohexanone (ACHE) was studied in water under different experimental conditions. By contrast with other previously studied beta-diketones, the keto-enol interconversion in the ACHE system is a slow process. Under equilibrium conditions, the analysis of the absorbance
Cédric Bouteiller et al.
Organic & biomolecular chemistry, 8(5), 1111-1120 (2010-02-19)
An operationally simple and concise synthesis of anilinoethanolamines, as NMDA NR2B receptor antagonist ifenprodil analogues, was developed via a copper-catalyzed amination of the corresponding bromoarene. Coupling was achieved with linear primary alkylamines, alpha,omega-diamines, hexanolamine and benzophenone imine, as well as
Emilia Iglesias
The Journal of organic chemistry, 68(7), 2689-2697 (2003-03-29)
The kinetic study of the nitrosation of the enol of 2-acetylcyclohexanone (ACHE) has been performed in aqueous acid media in the absence and presence of alpha- and beta-cyclodextrin. The reaction is first-order with respect to both reactants concentration: [nitrite] and
Zhiyu Jia et al.
Angewandte Chemie (International ed. in English), 53(42), 11298-11301 (2014-09-10)
The α-arylation of carbonyl compounds is generally accomplished under basic conditions, both under metal catalysis and via aryl transfer from the diaryl λ(3)-iodanes. Here, we describe an alternative metal-free α-arylation using ArI(O2CCF3)2 as the source of a 2-iodoaryl group. The
Masaharu Fujita et al.
Journal of applied toxicology : JAT, 39(2), 191-208 (2018-09-18)
The amino acid derivative reactivity assay (ADRA) is an in chemico alternative to animal testing for skin sensitization that solves certain problems found in the use of the direct peptide reactivity assay (DPRA). During a recent validation study conducted at

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