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167185

Sigma-Aldrich

Methyl 2-bromopropionate

98%

Sinonimo/i:

(±)-2-Bromopropionic acid methyl ester, (±)-Methyl 2-bromopropionate, 2-Bromopropanoic acid methyl ester, 2-Bromopropionic acid methyl ester, Methyl (±)-α-bromopropionate

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About This Item

Formula condensata:
CH3CHBrCO2CH3
Numero CAS:
5445-17-0
Peso molecolare:
167.00
Beilstein:
1720592
Numero CE:
226-642-3
Numero MDL:
MFCD00000143
Codice UNSPSC:
12352100
ID PubChem:
24850199
NACRES:
NA.22

Saggio

98%

Forma fisica

liquid

Indice di rifrazione

n20/D 1.451 (lit.)

P. eboll.

51 °C/19 mmHg (lit.)

Solubilità

water: insoluble

Densità

1.497 g/mL at 25 °C (lit.)

Gruppo funzionale

bromo

Stringa SMILE

COC(=O)C(C)Br

InChI

1S/C4H7BrO2/c1-3(5)4(6)7-2/h3H,1-2H3
ACEONLNNWKIPTM-UHFFFAOYSA-N

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Categorie correlate

Applicazioni

Methyl 2-bromopropionate was used as initiator during the synthesis of polymer brushes with single-walled carbon nanotubes as backbones. It was used as starting reagent for the synthesis of 2-18F-fluoropropionic acid, positron emission tomography imaging agent for prostate cancer.

Avvertenze

Danger

Indicazioni di pericolo

H226,H314,H335

Classi di pericolo

Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

125.6 °F - closed cup

Punto d’infiammabilità (°C)

52 °C - closed cup

Dispositivi di protezione individuale

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificati d'analisi (COA)

Lot/Batch Number
MKCQ1860
MKCM4075
MKCJ7662
MKCL1595
MKCH6296

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Gerard Lligadas et al.
Biomacromolecules, 18(10), 2981-3008 (2017-08-30)
The most fundamental aspects of single-electron transfer (SET) principles are presented. They are discussed according to different definitions used by expert practitioners and are applied to SET living radical polymerization (SET-LRP) according to the definition of the division of organic
Nagavarakishore Pillarsetty et al.
Journal of nuclear medicine : official publication, Society of Nuclear Medicine, 50(10), 1709-1714 (2009-09-18)
There is a high interest in developing an (18)F-labeled PET tracer that can aid in diagnosis and therapy monitoring of prostate cancer. In the current study, we have evaluated the potential of 2-(18)F-fluoropropionic acid ((18)F-FPA) as a PET tracer for
Shuhui Qin et al.
Journal of the American Chemical Society, 126(1), 170-176 (2004-01-08)
Polymer brushes with single-walled carbon nanotubes (SWNT) as backbones were synthesized by grafting n-butyl methacrylate (nBMA) from the ends and sidewalls of SWNT via atom transfer radical polymerization (ATRP). Carboxylic acid groups on SWNT were formed by nitric acid oxidation.
Yu Wang
Polymers, 11(8) (2019-07-31)
Atom transfer radical polymerization (ATRP) of methyl acrylate (MA) was carried out by continuous feeding of Cu(I) activators. Typically, the solvent, the monomer, the initiator, and the CuBr2/Me6TREN deactivator are placed in a Schlenk flask (Me6TREN: tris[2-(dimethylamino)ethyl]amine), while the CuBr/Me6TREN
Federico Di Sacco et al.
Nanomaterials (Basel, Switzerland), 9(3) (2019-03-22)
Novel, multipurpose terpolymers based on styrene (PS), tert-butyl methacrylate (tBMA) and glycidyl methacrylate (GMA), have been synthesized via Atom Transfer Radical Polymerization (ATRP). Post-synthetic modification with 1-pyrenemethylamine (AMP) allows non-covalent functionalization of carbon nanotubes, eventually yielding a conductive nanocomposite materials
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