136824
3,3-Dimethyl-2-butanol
98%
Sinonimo/i:
tert-Butyl methyl carbinol, Pinacoline alcohol, Pinacolyl alcohol
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About This Item
Prodotti consigliati
Livello qualitativo
Saggio
98%
Forma fisica
liquid
Indice di rifrazione
n20/D 1.415 (lit.)
P. eboll.
119-121 °C (lit.)
Punto di fusione
4.8 °C (lit.)
Densità
0.812 g/mL at 25 °C (lit.)
Gruppo funzionale
hydroxyl
Stringa SMILE
CC(O)C(C)(C)C
InChI
1S/C6H14O/c1-5(7)6(2,3)4/h5,7H,1-4H3
DFOXKPDFWGNLJU-UHFFFAOYSA-N
Descrizione generale
3,3-Dimethyl-2-butanol is a potential precursor for prohibited chemical weapons such as soman, a nerve agent. It is a synthetic analog of kairomone.
Applicazioni
3,3-Dimethyl-2-butanol (pinacolyl alcohol) can be used as a substrate:
- To study the oxidation of secondary alcohols to ketones using cyclic microwave heating technique.
- To prepare aryl ethers by reacting with aryl iodide using 4-pyrrolidinopyridine ligand via Cu-catalyzed Ullmann reaction.
3,3-Dimethyl-2-butanol was used in conversion of ribose- and glucose-binding proteins into receptors for pinacolyl methyl phosphonic acid.
Avvertenze
Warning
Indicazioni di pericolo
Consigli di prudenza
Classi di pericolo
Flam. Liq. 3
Codice della classe di stoccaggio
3 - Flammable liquids
Classe di pericolosità dell'acqua (WGK)
WGK 3
Punto d’infiammabilità (°F)
78.8 °F - closed cup
Punto d’infiammabilità (°C)
26 °C - closed cup
Dispositivi di protezione individuale
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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I clienti hanno visto anche
Chemical ionization mass spectral analysis of pinacolyl alcohol and development of derivatization method using p-tolyl isocyanate.
Analytical Methods : Advancing Methods and Applications, 2(10), 1599-1605 (2010)
Fast oxidation of secondary alcohols by the bromate-bromide system using cyclic microwave heating in acidic water
Tetrahedron Letters, 51(51), 6695-6699 (2010)
Journal of applied toxicology : JAT, 7(5), 307-312 (1987-10-01)
Sprague-Dawley rats were given 15, 70 and 140 min exposures to 15 mg/l 3,3-dimethyl-2-butanol, pinacolyl alcohol (PA), or 6-hour exposures to 0.2, 1.0 and 5.0 mg/l PA (1 mg/l = 240 ppm). A 50% mortality rate was obtained at the
Ullmann CO coupling of sterically hindered secondary alcohols using excess amount of strongly coordinating monodentate ligands
Tetrahedron Letters, 58(10), 1015-1019 (2017)
Biochemical pharmacology, 46(11), 2083-2092 (1993-12-03)
Soman (pinacolyl methylphosphonofluoridate), a highly toxic organophosphate compound, has been found to be a strong inhibitor of hepatic microsomal carboxylesterase in vitro, but an enhancer of carboxylesterase when administered in vivo. In response to this paradoxical observation, the objective of
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